(en)The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags. Such malodor control technologies do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

1.ApplicationNumber: US-201715407477-A
1.PublishNumber: US-2017119917-A1
2.Date Publish: 20170504
3.Inventor: FRANKENBACH GAYLE MARIE
HOLLINGSHEAD JUDITH ANN
HORENZIAK STEVEN ANTHONY
MADHAV PRAKASH J.
STANTON DAVID THOMAS
READNOUR CHRISTINE MARIE
LIU ZAIYOU
CETTI JONATHAN ROBERT

4.Inventor Harmonized: FRANKENBACH GAYLE MARIE(US)
HOLLINGSHEAD JUDITH ANN(US)
HORENZIAK STEVEN ANTHONY(US)
MADHAV PRAKASH J(US)
STANTON DAVID THOMAS(US)
READNOUR CHRISTINE MARIE(US)
LIU ZAIYOU(US)
CETTI JONATHAN ROBERT(US)

5.Country: US
6.Claims:
(en)The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags. Such malodor control technologies do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.

7.Description:
(en)FIELD OF THE INVENTION
The present invention relates to malodor reduction compositions and methods of making and using same.
BACKGROUND OF THE INVENTION
Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C 2 -C 12 carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.
Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. Thus, the malodor control technologies disclosed herein do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
SUMMARY OF THE INVENTION
The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags. Such malodor control technologies do not unduely interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.


DETAILED DESCRIPTION OF THE INVENTION
As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein “consumer product” means baby care, beauty care, fabric & home care, family care, feminine care, health care, snack and/or beverage products or devices. Such products include but are not limited to plastic films garbage bags, storage bags, storage wraps, diapers, bibs, wipes, garments, textiles including sheets and towels, composters; products for and/or methods relating to treating hair (human, dog, and/or cat), including, bleaching, coloring, dyeing, conditioning, wet or dry shampooing, styling, scalp treatments; deodorants and antiperspirants; personal cleansing; cosmetics; skin care including application of creams, lotions, fine fragrances and other topically applied products for consumer use; and shaving products, products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including: air care including air filtration, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, towel bowl cleaners and other cleaning and/or malodor treatments for consumer, agricultural, industrial or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening.
As used herein “energized system”, refers to a system that operates by using an electrical and/or mechanical energy source such as a battery or electrical wall outlet to emit the malodor reduction composition. Examples of such devices include but are limited to liquid electric pluggable type air freshening devices.
As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, “neutralize” or “neutralization” refers to the ability of a compound or product to reduce or eliminate malodorous compounds. Odor neutralization may be partial, affecting only some of the malodorous compounds in a given context, or affecting only part of a malodorous compound. A malodorous compound may be neutralized by chemical reaction resulting in a new chemical entity, by sequestration, by chelation, by association, or by any other interaction rendering the malodorous compound less malodorous or non-malodorous. Neutralization is distinguishable from odor masking or odor blocking by a change in the malodorous compound, as opposed to a change in the ability to perceive the malodor without any corresponding change in the condition of the malodorous compound. Malodor neutralization provides a sensory and analytically measurable (e.g. gas chromatograph) malodor reduction. Thus, if a malodor reduction composition delivers genuine malodor neutralization, the composition will reduce malodors in the vapor and/or liquid phase.
As used herein, “non-energized” refers to a system that emits a targeted active passively or without the need for an electrical energy source. Handheld aerosol sprayers and traditional trigger/pump sprayers are considered non-energized systems.
As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.
As used herein, “odor masking” refers to the ability of a compound with a non-offensive or pleasant smell that is dosed such that it limits the ability to sense a malodorous compound. Odor-masking may involve the selection of compounds which coordinate with an anticipated malodor to change the perception of the overall scent provided by the combination of odorous compounds.
As used herein, the terms “a” and “an” mean “at least one”.
As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Malodor Reduction Materials








Codes









A = Vapor Pressure >0.1 torr


B = Vapor Pressure is between 0.01 torr and 0.1 torr


C = ClogP <3


D = ClogP >3


E = Probability of Ingredient Color Instability = 0%


F = Probability of Ingredient Color Instability <71%


G = Odor Detection Threshold less than p.ol = 8


H = Odor Detection Threshold greater than p.ol = 8


I = Melamine formaldehyde PMC Headspace Response


Ratio greater than or equal to 10


J = Melamine formaldehyde PMC leakage less than or


equal to 5%


K = Log of liquid dish neat product liquid-air partition


coefficient greater than or equal to −7


L = Log of liquid dish neat product liquid-air partition


coefficient greater than or equal to −5









































TABLE 1



List of materials with at least one MORV from 1 to 5






Num-

CAS
Comment

ber
Material Name
Number
Code








1
2-ethylhexyl (Z)-3-(4-
5466-77-3
DEFHJ


methoxyphenyl)acrylate

2
2,4-dimethyl-2-(5,5,8,8-tetramethyl-
131812-67-4
DFHJ


5,6,7,8-tetrahydronaphthalen-2-yl)-


1,3-dioxolane

3
1,1-dimethoxynon-2-yne
13257-44-8
ACEFHJK

4
para-Cymen-8-ol
1197-01-9
BCGIJK

7
3-methoxy-7,7-dimethyl-10-
216970-21-7
BDEFHJK


methylenebicyclo[4.3.1]decane

9
Methoxycyclododecane
2986-54-1
DEFHJK

10
1,1-dimethoxycyclododecane
950-33-4
DEFHJK

11
(Z)-tridec-2-enenitrile
22629-49-8
DEFHJK

13
Oxybenzone
131-57-7
DEFGJ

14
Oxyoctaline formate
65405-72-3
DFHJK

16
4-methyl-1-oxaspiro[5.5]undecan-4-
57094-40-3
CFGIJK


ol

17
7-methyl-2H-benzo[b][1,4]dioxepin-
28940-11-6
CGIK


3(4H)-one

18
1,8-dioxacycloheptadecan-9-one
1725-01-5
DGJ

21
4-(tert-pentyl)cyclohexan-1-one
16587-71-6
ADFGIJKL

22
o-Phenyl anisol
86-26-0
DEFHJK

23
3a,5,6,7,8,8b-hexahydro-
823178-41-2
DEFHJK


2,2,6,6,7,8,8-heptamethyl-4H-


indeno(4,5-d)-1,3-dioxole

25
7-isopropyl-8,8-dimethyl-6,10-
62406-73-9
BDEFHIJK


dioxaspiro[4.5]decane

28
Octyl 2-furoate
39251-88-2
DEFHJK

29
Octyl acetate
112-14-1
BDEFHJKL

30
octanal propylene glycol acetal
74094-61-4
BDEFHJKL

31
Octanal
124-13-0
ACHIKL

32
Octanal dimethyl acetal
10022-28-3
ACEFGJKL

33
Myrcene
123-35-3
ADEFGIKL

34
Myrcenol
543-39-5
BCEFGIJK

35
Myrcenyl acetate
1118-39-4
ADEFGJK

36
Myristaldehyde
124-25-4
DFHJK

37
Myristicine
607-91-0
CGJK

38
Myristyl nitrile
629-63-0
DEFHJK

39
2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-
103614-86-4
DEFHIJK


octahydronaphthalen-1-ol

42
Ocimenol
5986-38-9
BCHIJK

43
Ocimenol
28977-58-4
BCHIJK

47
Nopyl acetate
128-51-8
DEFHJK

48
Nootkatone
4674-50-4
DHJK

49
Nonyl alcohol
143-08-8
BDEFGIJKL

50
Nonaldehyde
124-19-6
ADHIKL

52
12-methyl-14-tetradec-9-enolide
223104-61-8
DFHJK

57
N-ethyl-p-menthane-3-carboxamide
39711-79-0
DEFGIJK

61
1-(3-methylbenzofuran-2-yl)ethan-1-
23911-56-0
CEFHIK


one

62
2-methoxynaphthalene
93-04-9
BDEFHK

63
Nerolidol
7212-44-4
DEFHJK

64
Nerol
106-25-2
BCHIK

65
1-ethyl-3-
31996-78-8
ACEFHIJKL


methoxytricyclo[2.2.1.02,6]heptane

67
Methyl (E)-non-2-enoate
111-79-5
ADEFHJKL

68
10-isopropyl-2,7-dimethyl-1-
89079-92-5
BDEFHIJK


oxaspiro[4.5]deca-3,6-diene

69
2-(2-(4-methylcyclohex-3-en-1-
95962-14-4
DHJK


yl)propyl)cyclopentan-1-one

70
Myrtenal
564-94-3
ACFHIJKL

71
(E)-4-(2,2,3,6-
54992-90-4
BDEFHIJK


tetramethylcyclohexyl)but-3-en-2-


one

74
Myraldyl acetate
53889-39-7
DHJK

75
Musk tibetine
145-39-1
DHIJ

76
1,7-dioxacycloheptadecan-8-one
3391-83-1
DGJ

77
Musk ketone
81-14-1
DHJ

78
Musk ambrette
83-66-9
DHIJ

79
3-methylcyclopentadecan-1-one
541-91-3
DEFHJK

80
(E)-3-methylcyclopentadec-4-en-1-
82356-51-2
DHJK


one

82
3-methyl-4-phenylbutan-2-ol
56836-93-2
BCEFHIK

83
1-(4-isopropylcyclohexyl)ethan-1-ol
63767-86-2
BDEFHIJK

85
Milk Lactone
72881-27-7
DEFHJK

91
Methyl octine carbonate
111-80-8
BDEFHKL

92
Methyl octyl acetaldehyde
19009-56-4
ADFHJKL

93
6,6-dimethoxy-2,5,5-trimethylhex-2-
67674-46-8
ACHIJKL


ene

98
Methyl phenylethyl carbinol
2344-70-9
BCEFHIK

100
Methyl stearate
112-61-8
DEFHJ

101
Methyl nonyl acetaldehyde dimethyl
68141-17-3
BDEFHJK


acetal

102
Methyl nonyl ketone
112-12-9
BDFHJKL

103
Methyl nonyl acetaldehyde
110-41-8
BDFHJK

104
Methyl myristate
124-10-7
DEFHJK

105
Methyl linoleate
112-63-0
DEFHJ

106
Methyl lavender ketone
67633-95-8
CFHJK

108
Methyl isoeugenol
93-16-3
ACEFHK

109
Methyl hexadecanoate
112-39-0
DEFHJK

110
Methyl eugenol
93-15-2
ACEFHK

112
Methyl epijasmonate
1211-29-6
CHJK

113
Methyl dihydrojasmonate
24851-98-7
DFHJK

114
Methyl diphenyl ether
3586-14-9
DEFHJK

117
Methyl cinnamate
103-26-4
BCEFHK

119
Methyl chavicol
140-67-0
ADEFHK

120
Methyl beta-naphthyl ketone
93-08-3
CEFHK

122
Methyl 2-octynoate
111-12-6
ACEFHKL

123
Methyl alpha-cyclogeranate
28043-10-9
ACHIJKL

126
Methoxycitronellal
3613-30-7
ACFGIJK

128
Menthone 1,2-glycerol ketal
67785-70-0
CEFHJ


(racemic)

130
Octahydro-1H-4,7-methanoindene-1-
30772-79-3
BCFHIJKL


carbaldehyde

134
3-(3-(tert-butyl)phenyl)-2-
62518-65-4
BDHJK


methylpropanal

135
(E)-4-(4,8-dimethylnona-3,7-dien-1-
38462-23-6
DEFHJK


yl)pyridine

137
(E)-trideca-3,12-dienenitrile
134769-33-8
DEFHJK

140
2,2-dimethyl-3-(m-tolyl)propan-1-ol
103694-68-4
CEFHIJK

141
2,4-dimethyl-4,4a,5,9b-
27606-09-3
CEFHJK


tetrahydroindeno[1,2-d][1,3]dioxine

142
Maceal
67845-30-1
BDFHJK

143
4-(4-hydroxy-4-
31906-04-4
CHJ


methylpentyl)cyclohex-3-ene-1-


carbaldehyde

145
l-Limonene
5989-54-8
ADEFGIJKL

146
(Z)-3-hexen-1-yl-2-cyclopenten-1-
53253-09-1
BDHK


one

148
Linalyl octanoate
10024-64-3
DEFHJ

149
Linalyl isobutyrate
78-35-3
BDHJK

152
Linalyl benzoate
126-64-7
DFHJ

153
Linalyl anthranilate
7149-26-0
DFHJ

155
Linalool oxide (furanoid)
60047-17-8
BCHIJK

156
linalool oxide
1365-19-1
CGIJK

158
(2Z,6E)-3,7-dimethylnona-2,6-
61792-11-8
BDEFHJK


dienenitrile

159
3-(4-methylcyclohex-3-en-1-
6784-13-0
ACFHIJK


yl)butanal

161
(2,5-dimethyl-1,3-dihydroinden-2-
285977-85-7
CEFHJK


yl)methanol

162
3-(4-(tert-butyl)phenyl)-2-
80-54-6
BDHJK


methylpropanal

167
(E)-1-(1-methoxypropoxy)hex-3-ene
97358-54-8
ACEFGJKL

168
Leaf acetal
88683-94-7
ACEFGJKL

170
l-Carveol
2102-58-1
BCHIJK

174
Lauryl alcohol
112-53-8
DEFGJK

175
Lauryl acetate
112-66-3
DEFHJK

176
Lauric acid
143-07-7
DEFHJ

177
Lactojasmone
7011-83-8
BDEFHIJKL

178
Lauraldehyde
112-54-9
BDFHJK

179
3,6-dimethylhexahydrobenzofuran-
92015-65-1
BCEFHIJKL


2(3H)-one

182
4-(1-ethoxyvinyl)-3,3,5,5-
36306-87-3
BDFHIJK


tetramethylcyclohexan-1-one

183
Khusimol
16223-63-5
CEFHJK

184
5-(sec-butyl)-2-(2,4-
117933-89-8
DEFHJ


dimethylcyclohex-3-en-1-yl)-5-


methyl-1,3-dioxane

185
(1-methyl-2-((1,2,2-
198404-98-7
DEFHJK


trimethylbicyclo[3.1.0]hexan-3-


yl)methyl)cyclopropyl)methanol

186
2-propylheptanenitrile
208041-98-9
ADEFHIJKL

187
(E)-6-(pent-3-en-1-yl)tetrahydro-2H-
32764-98-0
BCFHIKL


pyran-2-one

189
2-hexylcyclopentan-1-one
13074-65-2
BDFHJKL

190
2-methyl-4-phenyl-1,3-dioxolane
33941-99-0
BCEFGIK

192
2,6,9,10-tetramethyl-1-
71078-31-4
BDEFHIJK


oxaspiro(4.5)deca-3,6-diene

193
Isopulegol
89-79-2
BCEFHIJKL

195
Isopropyl palmitate
142-91-6
DEFHJ

196
Isopropyl myristate
110-27-0
DEFHJK

197
Isopropyl dodecanoate
10233-13-3
DEFHJK

199
Isopimpinellin
482-27-9
CFGJ

206
Iso3-methylcyclopentadecan-1-one
3100-36-5
DEFGJK

208
Isomenthone
491-07-6
ADEFGIJKL

209
Isojasmone
95-41-0
BDFHJKL

210
Isomenthone
36977-92-1
ADEFGIJKL

211
Isohexenyl cyclohexenyl
37677-14-8
DFHJK


carboxaldehyde

212
Isoeugenyl benzyl ether
120-11-6
DFHJ

215
1-((2S,3S)-2,3,8,8-tetramethyl-
54464-57-2
DHJK


1,2,3,4,5,6,7,8-octahydronaphthalen-


2-yl)ethan-1-one

218
Isocyclocitral
1335-66-6
ACFHIJKL

221
Isobutyl quinoline
65442-31-1
DEFHJK

227
Isobornylcyclohexanol
68877-29-2
DEFHJK

228
Isobornyl propionate
2756-56-1
BDEFHIJK

229
Isobornyl isobutyrate
85586-67-0
BDEFHIJK

230
Isobornyl cyclohexanol
66072-32-0
DEFHJK

231
Isobornyl acetate
125-12-2
ADEFHIJKL

233
Isobergamate
68683-20-5
DEFHJK

234
Isoamyl undecylenate
12262-03-2
DEFHJK

238
Isoamyl laurate
6309-51-9
DEFHJK

242
Isoambrettolide
28645-51-4
DGJ

243
Irisnitrile
29127-83-1
ADEFHKL

244
Indolene
68527-79-7
DEFHJ

246
Indol/Hydroxycitronellal Schiff base
67801-36-9
DEFHJ

247
4,4a,5,9b-tetrahydroindeno[1,2-
18096-62-3
BCEFGJK


d][1,3]dioxine

249
Hydroxy-citronellol
107-74-4
CEFGIJK

252
2-cyclododecylpropan-1-ol
118562-73-5
DEFHJK

253
Hydrocitronitrile
54089-83-7
CEFHJK

254
Hydrocinnamyl alcohol
122-97-4
BCEFHIK

256
Hydratropaldehyde dimethyl acetal
90-87-9
ACEFHJK

259
5-ethyl-4-hydroxy-2-methylfuran-
27538-09-6
CFGIK


3(2H)-one

260
2,3-dihydro-3,3-dimethyl-1H-indene-
173445-44-8
DHJK


5-propanal

261
3-(3,3-dimethyl-2,3-dihydro-1H-
173445-65-3
DHJK


inden-5-yl)propanal

263
Hexyl octanoate
1117-55-1
DEFHJK

267
Hexyl hexanoate
6378-65-0
DEFHJKL

269
Hexyl cinnamic aldehyde
101-86-0
DHJ

271
Hexyl benzoate
6789-88-4
DEFHJK

274
Hexenyl tiglate
84060-80-0
BDEFHJK

276
(E)-3,7-dimethylocta-2,6-dien-1-yl
3681-73-0
DEFHJ


palmitate

277
Hexadecanolide
109-29-5
DEFGJK

278
2-butyl-4,4,6-trimethyl-1,3-dioxane
54546-26-8
ADEFHIJKL

280
Ethyl (1R,2R,3R,4R)-3-
116126-82-0
BDEFHIJK


isopropylbicyclo[2.2.1]hept-5-ene-2-


carboxylate

281
3a,4,5,6,7,7a-hexahydro-1H-4,7-
5413-60-5
CEFGJK


methanoinden-6-yl acetate

285
2-(1-(3,3-
141773-73-1
DEFHJ


dimethylcyclohexyl)ethoxy)-2-


methylpropyl propionate

286
Heliotropine diethyl acetal
40527-42-2
CEFGJ

288
Helional
1205-17-0
CHJK

289
(E)-oxacyclohexadec-13-en-2-one
111879-80-2
DGJK

290
Gyrane
24237-00-1
ADEFHIJKL

292
Guaiol
489-86-1
DEFHJK

293
1-(2,6,6-trimethylcyclohex-2-en-1-
68611-23-4
DHJK


yl)pentan-3-one

294
Ethyl 2-ethyl-6,6-dimethylcyclohex-
57934-97-1
BDEFHIJK


2-ene-1-carboxylate

295
Germacrene B
15423-57-1
DEFHJK

296
Germacrene D
23986-74-5
DEFHJK

300
Geranyl phenylacetate
102-22-7
DFHJ

301
Geranyl phenyl acetate
71648-43-6
DFHJ

303
Geranyl linalool
1113-21-9
DFHJ

307
Geranyl cyclopentanone
68133-79-9
DHJK

316
gamma-Undecalactone (racemic)
104-67-6
DEFHJKL

317
gamma-Terpinyl acetate
10235-63-9
BDHJK

318
gamma-Terpineol
586-81-2
BCGIJK

321
gamma-Nonalactone
104-61-0
BCEFHIKL

322
gamma-Muurolene
30021-74-0
DEFHJKL

323
gamma-(E)-6-(pent-3-en-1-
63095-33-0
BCEFHKL


yl)tetrahydro-2H-pyran-2-one

324
gamma-Ionone
79-76-5
BDEFHIJK

325
gamma-Himachalene
53111-25-4
BDEFHJKL

328
gamma-Gurjunene
22567-17-5
DEFHJKL

329
gamma-Eudesmol
1209-71-8
DFHJK

330
gamma-Dodecalactone
2305-05-7
DEFHJK

331
gamma-Damascone
35087-49-1
BDEFHIJK

332
gamma-Decalactone
706-14-9
BDEFHIJKL

333
gamma-Cadinene
39029-41-9
DEFHJKL

334
1-(3,3-dimethylcyclohexyl)pent-4-
56973-87-6
BDEFHJK


en-1-one

335
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-
1222-05-5
DEFHJK


hexahydrocyclopenta[g]isochromene

336
Furfuryl octanoate
39252-03-4
DEFHJK

338
Furfuryl hexanoate
39252-02-3
CEFHJK

339
Furfuryl heptanoate
39481-28-2
CEFHJK

342
2-methyldecanenitrile
69300-15-8
BDEFHJKL

343
8,8-dimethyl-3a,4,5,6,7,7a-
76842-49-4
DEFHJK


hexahydro-1H-4,7-methanoinden-6-


yl propionate

344
Ethyl (3aR,4S,7R,7aR)-octahydro-
80657-64-3
DEFHIJK


3aH-4,7-methanoindene-3a-


carboxylate

347
Diethyl cyclohexane-1,4-
72903-27-6
CEFHJK


dicarboxylate

349
(6-isopropyl-9-methyl-1,4-
63187-91-7
CEFHJ


dioxaspiro[4.5]decan-2-yl)methanol

350
2-isobutyl-4-methyltetrahydro-2H-
63500-71-0
BCEFHIJK


pyran-4-ol

352
Undec-10-enenitrile
53179-04-7
BDEFHJK

353
(Z)-6-ethylideneoctahydro-2H-5,8-
69486-14-2
CEFGJK


methanochromen-2-one

356
3-(2-ethylphenyl)-2,2-
67634-15-5
BDHJK


dimethylpropanal

358
(E)-4,8-dimethyldeca-4,9-dienal
71077-31-1
BDFHJK

359
(E)-4-((3aR,4R,7R,7aR)-
501929-47-1
DEFHJK


1,3a,4,6,7,7a-hexahydro-5H-4,7-


methanoinden-5-ylidene)-3-


methylbutan-2-ol

360
8,8-dimethyl-3a,4,5,6,7,7a-
171102-41-3
DEFHJK


hexahydro-1H-4,7-methanoinden-6-


yl acetate

361
3-(4-ethylphenyl)-2,2-
134123-93-6
DEFHJK


dimethylpropanenitrile

362
2-heptylcyclopentan-1-one
137-03-1
DFHJKL

363
1-ethoxyethoxy Cyclododecane
389083-83-4
DEFHJK

364
3-cyclohexene-1-carboxylic acid,
815580-59-7
ACHIJKL


2,6,6-trimethyl-, methyl ester

368
Farnesyl acetate
29548-30-9
DEFHJK

369
Farnesol
4602-84-0
DEFHJK

370
Oxacyclohexadecan-2-one
106-02-5
DEFGJK

371
1-cyclopentadec-4-en-1-one
14595-54-1
DEFGJK

372
1-cyclopentadec-4-en-1-one
35720-57-1
DEFGJK

373
2-methoxy-4-(4-
128489-04-3
CGJ


methylenetetrahydro-2H-pyran-2-


yl)phenol

374
Eugenyl acetate
93-28-7
CFHJK

375
Eugenol
97-53-0
CHIK

377
Ethylmethylphenylglycidate
77-83-8
CFHJK

378
Ethylene brassylate
105-95-3
DFGJ

381
Ethyl undecylenate
692-86-4
DEFHJK

385
Ethyl palmitate
628-97-7
DEFHJ

386
Ethyl nonanoate
123-29-5
BDEFHJKL

388
Ethyl myristate
124-06-1
DEFHJK

390
Ethyl linalool
10339-55-6
BCEFHJK

391
Ethyl laurate
106-33-2
DEFHJK

394
Ethyl hexyl ketone
925-78-0
ADFHIKL

397
Ethyl decanoate
110-38-3
BDEFHJK

398
Ethyl gamma-Safranate
35044-57-6
ADHIJK

407
Ethyl 3-phenylglycidate
121-39-1
CGJK

413
6-ethyl-2,10,10-trimethyl-1-
79893-63-3
BDEFHIJK


oxaspiro[4.5]deca-3,6-diene

414
Elemol
639-99-6
DEFHJK

415
(2-(1-ethoxyethoxy)ethyl)benzene
2556-10-7
BCEFHJK

416
(E)-3-methyl-5-(2,2,3-
67801-20-1
DHJK


trimethylcyclopent-3-en-1-yl)pent-4-


en-2-ol

417
d-xylose
58-86-6
CGIJ

418
(E)-4-((3aS,7aS)-octahydro-5H-4,7-
30168-23-1
DFHJK


methanoinden-5-ylidene)butanal

421
Dodecanal dimethyl acetal
14620-52-1
DEFHJK

424
d-Limonene
5989-27-5
ADEFGIJKL

425
Dipropylene Glycol
25265-71-8
CEFGIK

426
Dispirone
83863-64-3
BDEFHJK

428
Diphenyloxide
101-84-8
BDEFHK

429
Diphenylmethane
101-81-5
DEFGK

432
Dimethyl benzyl carbinyl butyrate
10094-34-5
DEFHJK

436
2,6-dimethyloct-7-en-4-one
1879-00-1
ADEFHIJKL

441
Octahydro-1H-4,7-methanoinden-5-
64001-15-6
DEFHJKL


yl acetate

444
Dihydrocarveol acetate
20777-49-5
BDEFHIJK

445
Dihydrocarveol
619-01-2
BCEFHIJKL

449
Dihydro Linalool
18479-51-1
BCEFGIJKL

450
Dihydro Isojasmonate
37172-53-5
DHJK

453
Dibutyl sulfide
544-40-1
ADEFHIKL

457
Dibenzyl
103-29-7
DEFGJK

459
delta-Undecalactone
710-04-3
DEFHJKL

461
delta-Elemene
20307-84-0
BDEFHJK

462
delta-Guaiene
3691-11-0
DEFHJKL

463
delta-Dodecalactone
713-95-1
DEFHJK

464
delta-Decalactone
705-86-2
BDEFHIJKL

465
delta-Cadinene
483-76-1
DEFHJKL

466
delta-damascone
57378-68-4
ADHIJK

467
delta-Amorphene
189165-79-5
DEFHJKL

468
delta-3-Carene
13466-78-9
ADEFGIJKL

470
Decylenic alcohol
13019-22-2
BDEFHJK

471
Decyl propionate
5454-19-3
DEFHJK

473
Decanal diethyl acetal
34764-02-8
DEFHJK

474
Decahydro-beta-naphthol
825-51-4
BCEFGIK

475
1-cyclohexylethyl (E)-but-2-enoate
68039-69-0
BDFHJK

478
3-(4-isopropylphenyl)-2-
103-95-7
BDFHJK


methylpropanal

479
Cyclotetradecane
295-17-0
DEFGJKL

480
Cyclopentadecanone
502-72-7
DEFGJK

482
Cyclohexyl salicylate
25485-88-5
DFGJ

484
3a,4,5,6,7,7a-hexahydro-1H-4,7-
113889-23-9
DEFHJK


methanoinden-6-yl butyrate

485
Cyclic ethylene dodecanedioate
54982-83-1
DFGJ

486
8,8-dimethyl-1,2,3,4,5,6,7,8-
68991-97-9
DHJK


octahydronaphthalene-2-


carbaldehyde

487
3a,4,5,6,7,7a-hexahydro-1H-4,7-
67634-20-2
DEFHJK


methanoinden-5-yl isobutyrate

488
Curzerene
17910-09-7
DHJK

491
Cumic alcohol
536-60-7
CHIJK

493
Coumarone
1646-26-0
BCEFHIK

497
2-(3-phenylpropyl)pyridine
2110-18-1
CEFHJK

498
Dodecanenitrile
2437-25-4
DEFHJK

501
(E)-cycloheptadec-9-en-1-one
542-46-1
DEFGJ

502
Citryl acetate
6819-19-8
DFHJK

503
Citrus Propanol
15760-18-6
CEFHIJK

505
Citronitrile
93893-89-1
CEFHJK

519
Citral propylene glycol acetal
10444-50-5
CEFHJK

520
Citral dimethyl acetal
7549-37-3
BCEFHJK

521
Citral diethyl acetal
7492-66-2
BDEFHJK

524
cis-Ocimene
3338-55-4
ADGIKL

527
cis-Limonene oxide
13837-75-7
ADEFGIJKL

529
Cis-iso-ambrettolide
36508-31-3
DGJ

530
cis-6-nonenol
35854-86-5
BCEFHIKL

531
cis-carveol
1197-06-4
BCHIJK

532
cis-4-Decen-1-al
21662-09-9
ADHKL

534
cis-3-hexenyl-cis-3-hexenoate
61444-38-0
BDEFHJK

537
cis-3-Hexenyl salicylate
65405-77-8
DEFGJ

541
Cis-3-hexenyl Benzoate
25152-85-6
DEFHJK

544
cis-3-Hexenyl 2-methylbutyrate
53398-85-9
ADEFHJKL

546
cis-3, cis-6-nonadienol
53046-97-2
ACEFHK

548
Cinnamyl propionate
103-56-0
DEFHJK

550
Cinnamyl isobutyrate
103-59-3
DEFHJK

551
Cinnamyl formate
104-65-4
BCEFHK

552
Cinnamyl cinnamate
122-69-0
DHJ

553
Cinnamyl acetate
103-54-8
BCEFHK

555
Cinnamic alcohol
104-54-1
BCEFHIK

558
Cetyl alcohol
36653-82-4
DEFHJ

559
(E)-1-(2,6,6-trimethylcyclohex-2-en-
79-78-7
DHJK


1-yl)hepta-1,6-dien-3-one

560
2-methyl-4-(2,6,6-trimethylcyclohex-
65405-84-7
DFHJK


1-en-1-yl)butanal

561
(3aR,5aR,9aR,9bR)-3a,6,6,9a-
3738-00-9
DEFHJK


tetramethyldodecahydronaphtho[2,1-


b]furan

562
1,6-dioxacycloheptadecan-7-one
6707-60-4
DGJ

563
1-(6-(tert-butyl)-1,1-dimethyl-2,3-
13171-00-1
DEFHJK


dihydro-1H-inden-4-yl)ethan-1-one

565
Cedryl methyl ether
19870-74-7
ADEFHJK

566
Cedryl formate
39900-38-4
BDEFHJK

567
Cedryl acetate
77-54-3
DEFHJK

568
(4Z,8Z)-1,5,9-trimethyl-13-
71735-79-0
DFHJK


oxabicyclo[10.1.0]trideca-4,8-diene

569
Cedrol
77-53-2
DEFHJK

570
5-methyl-1-(2,2,3-
139539-66-5
DEFHJK


trimethylcyclopent-3-en-1-yl)-6-


oxabicyclo[3.2.1]octane

571
5-methyl-1-(2,2,3-
426218-78-2
DFHJ


trimethylcyclopent-3-en-1-yl)-6-


oxabicyclo[3.2.1]octane

572
1,1,2,3,3-pentamethyl-1,2,3,5,6,7-
33704-61-9
BDEFHIJK


hexahydro-4H-inden-4-one

573
Caryophyllene alcohol acetate
32214-91-8
DEFHJK

574
Caryolan-1-ol
472-97-9
DEFHJK

577
Carvyl acetate
97-42-7
BDHIJK

578
Caprylnitrile
124-12-9
ACEFGIKL

580
Caprylic alcohol
111-87-5
ACEFGIKL

581
Caprylic acid
124-07-2
BCEFHIK

582
Capric acid
334-48-5
DEFHJK

584
Capraldehyde
112-31-2
ADHKL

586
3-(4-methoxyphenyl)-2-
5462-06-6
BCHJK


methylpropanal

587
Camphorquinone
10373-78-1
ACEFGIJK

589
Camphene
79-92-5
ADEFGIJKL

591
Ethyl 2-methyl-4-oxo-6-
59151-19-8
DHJ


pentylcyclohex-2-ene-1-carboxylate

592
Butylated hydroxytoluene
128-37-0
DEFGIJK

594
Butyl stearate
123-95-5
DEFHJ

595
Butyl butyryl lactate
7492-70-8
CEFGJK

599
Butyl 10-undecenoate
109-42-2
DEFHJK

600
2-methyl-4-(2,2,3-
72089-08-8
DEFHJK


trimethylcyclopent-3-en-1-yl)butan-


1-ol

601
3-(4-(tert-butyl)phenyl)propanal
18127-01-0
BDHJK

603
Bornyl isobutyrate
24717-86-0
BDEFHIJK

604
Bornyl acetate
76-49-3
ADEFHIJKL

606
2-ethoxy-2,6,6-trimethyl-9-
68845-00-1
BDEFHJK


methylenebicyclo[3.3.1]nonane

607
(ethoxymethoxy)cyclododecane
58567-11-6
DEFHJK

608
Bisabolene
495-62-5
DEFHJK

609
Bigarade oxide
72429-08-4
ADEFHJKL

610
beta-Vetivone
18444-79-6
DHJK

611
beta-Terpinyl acetate
10198-23-9
BDHJK

612
beta-Terpineol
138-87-4
BCGIJK

613
beta-Sinensal
60066-88-8
DHJK

614
beta-Sesquiphellandrene
20307-83-9
DEFHJK

615
beta-Selinene
17066-67-0
BDEFGJK

616
beta-Santalol
77-42-9
DEFHJK

618
beta-Pinene
127-91-3
ADEFGIJKL

620
beta-Naphthyl ethyl ether
93-18-5
BDEFHJK

621
beta-Patchoulline
514-51-2
BDEFGJKL

624
beta-Himachalene Oxide
57819-73-5
BDFHJK

625
beta-Himachalene
1461-03-6
DEFHJKL

626
beta-Guaiene
88-84-6
DEFHJKL

627
(2,2-dimethoxyethyl)benzene
101-48-4
DHJK

628
beta-Farnesene
18794-84-8
DEFHJK

631
beta-Copaene
18252-44-3
BDEFHJKL

632
beta-Cedrene
546-28-1
BDEFGJKL

633
beta-Caryophyllene
87-44-5
DEFHJKL

635
beta-Bisabolol
15352-77-9
DFHJK

636
Beta ionone epoxide
23267-57-4
BDEFHIJK

638
Bergaptene
484-20-8
CGJ

639
Benzyl-tert-butanol
103-05-9
CEFGJK

644
Benzyl laurate
140-25-0
DEFHJ

649
Benzyl dimethyl carbinol
100-86-7
BCEFGIK

650
Benzyl cinnamate
103-41-3
DHJ

653
Benzyl benzoate
120-51-4
DHJ

655
Benzophenone
119-61-9
DEFHK

658
7-isopentyl-2H-
362467-67-2
DHJ


benzo[b][1,4]dioxepin-3(4H)-one

659
2′-isopropyl-1,7,7-
188199-50-0
DEFHJK


trimethylspiro[bicyclo[2.2.1]heptane-


2,4′-[1,3]dioxane]

660
4-(4-methylpent-3-en-1-yl)cyclohex-
21690-43-7
DEFHJK


3-ene-1-carbonitrile

661
Aurantiol
89-43-0
DEFHJ

663
Anisyl phenylacetate
102-17-0
DFHJ

668
Methyl (E)-octa-4,7-dienoate
189440-77-5
ACEFHKL

671
Amyl Cinnamate
3487-99-8
DEFHJK

673
(3aR,5aS,9aS,9bR)-3a,6,6,9a-
6790-58-5
DEFHJK


tetramethyldodecahydronaphtho[2,1-


b]furan

674
(4aR,5R,7aS,9R)-2,2,5,8,8,9a-
211299-54-6
DEFHJK


hexamethyloctahydro-4H-4a,9-


methanoazuleno[5,6-d][1,3]dioxole

675
2,5,5-trimethyl-1,2,3,4,5,6,7,8-
71832-76-3
DEFHJK


octahydronaphthalen-2-ol

676
2,5,5-trimethyl-1,2,3,4,5,6,7,8-
41199-19-3
DEFHJK


octahydronaphthalen-2-ol

677
1-((2-(tert-
139504-68-0
DEFHJK


butyl)cyclohexyl)oxy)butan-2-ol

678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-
57345-19-4
DEFHJ


tetramethyldodecahydro-5H-3,5a-


epoxynaphtho[2,1-c]oxepine

679
2,2,6,6,7,8,8-heptamethyldecahydro-
476332-65-7
ADEFHJK


2H-indeno[4,5-b]furan

680
2,2,6,6,7,8,8-heptamethyldecahydro-
647828-16-8
ADEFHJK


2H-indeno[4,5-b]furan

681
Amber acetate
37172-02-4
BDEFHJK

682
Alpinofix
811436-82-5
DEFHJ

683
alpha-Thujone
546-80-5
ADEFGIJKL

684
alpha-Vetivone
15764-04-2
DHJK

686
alpha-Terpinyl propionate
80-27-3
BDEFHJK

691
alpha-Sinensal
17909-77-2
DHJK

692
alpha-Selinene
473-13-2
BDEFHJK

693
alpha-Santalene
512-61-8
ADEFHJKL

694
alpha-Santalol
115-71-9
DEFHJK

696
alpha-Patchoulene
560-32-7
ADEFHJKL

697
alpha-neobutenone
56973-85-4
BDHJK

698
alpha-Muurolene
10208-80-7
DEFHJKL

700
alpha-methyl ionone
127-42-4
BDHJK

702
alpha-Limonene
138-86-3
ADEFGIJKL

704
alpha-Irone
79-69-6
BDHJK

706
alpha-Humulene
6753-98-6
DEFHJK

707
alpha-Himachalene
186538-22-7
BDEFHJK

708
alpha-Gurjunene
489-40-7
BDEFHJKL

709
alpha-Guaiene
3691-12-1
DEFHJKL

710
alpha-Farnesene
502-61-4
DEFHJK

711
alpha-Fenchene
471-84-1
ADEFGIJKL

712
alpha-Eudesmol
473-16-5
DEFHJK

713
alpha-Curcumene
4176-17-4
DEFHJK

714
alpha-Cubebene
17699-14-8
ADEFHJKL

715
alpha-Cedrene epoxide
13567-39-0
ADEFHJK

716
alpha-Cadinol
481-34-5
DEFHJK

717
alpha-Cadinene
24406-05-1
DEFHJKL

718
alpha-Bisabolol
515-69-5
DFHJK

719
alpha-bisabolene
17627-44-0
DEFHJK

720
alpha-Bergamotene
17699-05-7
BDEFHJKL

721
alpha-Amylcinnamyl alcohol
101-85-9
DEFHJ

722
alpha-Amylcinnamyl acetate
7493-78-9
DEFHJ

723
alpha-Amylcinnamaldehyde diethyl
60763-41-9
DEFHJ


acetal

724
alpha-Amylcinnamaldehyde
122-40-7
DHJK

725
alpha-Amorphene
23515-88-0
DEFHJKL

726
alpha-Agarofuran
5956-12-7
BDEFHJK

727
1-methyl-4-(4-methyl-3-penten-1-
52475-86-2
DFHJK


yl)-3-Cyclohexene-1-carboxaldehyde

730
1-Phenyl-2-pentanol
705-73-7
CEFHK

731
1-Phenyl-3-methyl-3-pentanol
10415-87-9
CEFHJK

733
2,3,4-trimethoxy-benzaldehyde
2103-57-3
BCGI

735
2,4,5-trimethoxy-benzaldehyde
4460-86-0
BCG

736
2,4,6-trimethoxybenzaldehyde
830-79-5
BCGI

738
2,4-Nonadienal
6750-03-4
ACHKL

741
2,6,10-Trimethylundecanal
105-88-4
BDFGJK

742
alpha,4-Dimethyl benzenepropanal
41496-43-9
ACHJK

746
Allyl cyclohexyl propionate
2705-87-5
BDEFHJK

748
Allyl amyl glycolate
67634-00-8
BCEFGJK

750
Allo-aromadendrene
25246-27-9
BDEFHJKL

752
Aldehyde C-11
143-14-6
ADHJK

754
Methyl (E)-2-(((3,5-
94022-83-0
DEFHJ


dimethylcyclohex-3-en-1-


yl)methylene)amino)benzoate

757
2,6,10-trimethylundec-9-enal
141-13-9
BDFHJK

758
Acetoxymethyl-isolongifolene
59056-62-1
BDEFHJK


(isomers)

763
Acetate C9
143-13-5
BDEFHJKL

764
Acetarolle
744266-61-3
DFHJK

766
Acetaldehyde phenylethyl propyl
7493-57-4
CEFHJK


acetal

767
Acetaldehyde dipropyl acetal
105-82-8
ACEFGIKL

768
Acetaldehyde benzyl 2-methoxyethyl
7492-39-9
BCEFHJK


acetal

769
(Z)-2-(4-methylbenzylidene)heptanal
84697-09-6
DHJ

770
9-decenal
39770-05-3
ADHKL

771
8-Hexadecenolide
123-69-3
DGJ

772
7-Methoxycoumarin
531-59-9
CHK

774
7-epi-alpha-Selinene
123123-37-5
BDEFHJK

775
7-eip-alpha-Eudesmol
123123-38-6
DEFHJK

776
7-Acetyl-1,1,3,4,4,6-
1506-02-1
DEFHJ


hexamethyltetralin

778
6-Isopropylquinoline
135-79-5
CEFHJK

781
6,6-dimethyl-2-norpinene-2-
33885-51-7
BCFHJK


propionaldehyde

782
6,10,14-trimethyl-2-Pentadecanone
502-69-2
DEFHJK

786
5-Isopropenyl-2-methyl-2-
13679-86-2
ACGIJKL


vinyltetrahydrofuran

788
5-Cyclohexadecenone
37609-25-9
DEFGJK

791
4-Terpinenol
562-74-3
BCHIJK

792
4-Pentenophenone
3240-29-7
BCEFHIK

800
4-Carvomenthenol
28219-82-1
BCHIJK

802
4,5,6,7-Tetrahydro-3,6-
494-90-6
BCEFHIJKL


dimethylbenzofuran

803
4-(p-Methoxyphenyl)-2-butanone
104-20-1
BCEFHJK

804
3-Thujopsanone
25966-79-4
BDEFHJK

805
3-Propylidenephthalide
17369-59-4
CEFHK

806
3-Nonylacrolein
20407-84-5
BDFHJK

807
3-Methyl-5-phenyl-1-pentanal
55066-49-4
BDFHJK

814
3-Hexenyl isovalerate
10032-11-8
ADEFHJKL

821
3,6-Dimethyl-3-octanyl acetate
60763-42-0
ADEFHIJKL

824
3,4,5-trimethoxybenzaldehyde
86-81-7
BCGIK

826
3-(p-
7775-00-0
BDFHJK


Isopropylphenyl)propionaldehyde

827
2-Undecenenitrile
22629-48-7
BDEFHJK

828
2-Undecenal
2463-77-6
ADHJK

829
2-trans-6-trans-Nonadienal
17587-33-6
ACHKL

831
2-Phenylethyl butyrate
103-52-6
DEFHJK

833
2-Phenyl-3-(2-furyl)prop-2-enal
57568-60-2
CHJ

834
2-Phenoxyethanol
122-99-6
BCEFGIK

837
2-Nonen-1-al
2463-53-8
ADHKL

839
2-Nonanol
628-99-9
BDEFGIKL

840
2-Nonanone
821-55-6
ADFHIKL

849
2-Isobutyl quinoline
93-19-6
CEFHJK

850
2-Hexylidene cyclopentanone
17373-89-6
DFHJKL

852
2-Heptyl tetrahydrofuran
2435-16-7
BDEFHJKL

856
2-Decenal
3913-71-1
ADHKL

864
2,6-Nonadienal
26370-28-5
ACHKL

865
2,6-Nonadien-1-ol
7786-44-9
ACEFHK

866
2,6-dimethyl-octanal
7779-07-9
ADFGIJKL

868
1-Decanol
112-30-1
BDEFGJK

869
1-Hepten-1-ol, 1-acetate
35468-97-4
ACEFHKL

870
10-Undecen-1-ol
112-43-6
DEFHJK

871
10-Undecenal
112-45-8
ADHJK

872
10-epi-gamma-Eudesmol
15051-81-7
DFHJK

873
1,8-Thiocineol
68391-28-6
ADEFHIJKL

876
1,3,5-undecatriene
16356-11-9
ADEFHJKL

877
1,2-Dihydrolinalool
2270-57-7
BCEFGIJKL

878
1,3,3-trimethyl-2-norbornanyl
13851-11-1
ADEFHIJKL


acetate

879
1,1,2,3,3-Pentamethylindan
1203-17-4
ADHIJKL

881
(Z)-6,10-dimethylundeca-5,9-dien-2-
3239-37-0
DEFHJK


yl acetate

884
(Z)-3-Dodecenal
68141-15-1
BCFHJK

885
(S)-gamma-Undecalactone
74568-05-1
DEFHJKL

886
(R)-gamma-Undecalactone
74568-06-2
DEFHJKL

890
(E)-6,10-dimethylundeca-5,9-dien-2-
3239-35-8
DEFHJK


yl acetate

892
(2Z)-3-methyl-5-phenyl-2-
53243-59-7
DEFHJK


Pentenenitrile

893
(2S,5S,6S)-2,6,10,10-tetramethyl-1-
65620-50-0
DFHIJK


oxaspiro[4_5]decan-6-ol

894
(2E)-3-methyl-5-phenyl-2-
53243-60-0
CEFHJK


pentenenitrile

897
(+)-Dihydrocarveol
22567-21-1
BCEFHIJKL

905
Menthone
89-80-5
ADEFGIJKL

908
(R,E)-2-methyl-4-(2,2,3-
185068-69-3
CHJK


trimethylcyclopent-3-en-1-yl)but-2-


en-1-ol

912
2-(8-isopropyl-6-
68901-32-6
DEFHJK


methylbicyclo[2.2.2]oct-5-en-2-yl)-


1,3-dioxolane

913
gamma-methyl ionone
7388-22-9
BDHIJK

914
3-(3-isopropylphenyl)butanal
125109-85-5
BDHJK

916
3-(1-ethoxyethoxy)-3,7-
40910-49-4
BDEFHJK


dimethylocta-1,6-diene

919
3a,4,5,6,7,7a-hexahydro-1H-4,7-
17511-60-3
CEFHJK


methanoinden-6-yl propionate

920
Bulnesol
22451-73-6
DEFHJK

922
Benzyl phenylacetate
102-16-9
DHJ

923
Benzoin
119-53-9
CEFHJ

924
(E)-1,2,4-trimethoxy-5-(prop-1-en-1-
2883-98-9
BCFGJK


yl)benzene

925
alpha,alpha,6,6-tetramethyl
33885-52-8
BDFHJK


bicyclo[3.1.1]hept-2-ene-propanal

926
7-epi-sesquithujene
159407-35-9
DEFHJKL

927
5-Acetyl-1,1,2,3,3,6-
15323-35-0
DEFHJK


hexamethylindan

928
3-Methylphenethyl alcohol
1875-89-4
BCEFHIK

929
3,6-Nonadien-1-ol
76649-25-7
ACEFHK

930
2-Tridecenal
7774-82-5
BDFHJK

933
Patchouli alcohol
5986-55-0
DEFHIJK

937
p-Cresyl isobutyrate
103-93-5
BDHJK

939
p-Cresyl n-hexanoate
68141-11-7
DEFHJK

941
5-hexyl-4-methyldihydrofuran-
67663-01-8
BDEFHIJKL


2(3H)-one

942
Ethyl (2Z,4E)-deca-2,4-dienoate
3025-30-7
BDEFHJK

943
Pelargene
68039-40-7
DEFHJK

945
2-cyclohexylidene-2-
10461-98-0
DFHJK


phenylacetonitrile

946
Perillaldehyde
2111-75-3
ACHIJK

947
Perillyl acetate
15111-96-3
DFHJK

948
Perillyl alcohol
536-59-4
CHIJK

950
(2-isopropoxyethyl)benzene
68039-47-4
ACEFHJKL

951
Ethyl (2Z,4E)-deca-2,4-dienoate
313973-37-4
BDEFHJK

953
(2-(cyclohexyloxy)ethyl)benzene
80858-47-5
DEFHJK

954
Phenethyl 2-methylbutyrate
24817-51-4
DEFHJK

955
Phenethyl alcohol
60-12-8
BCEFGIK

959
Phenethyl phenylacetate
102-20-5
DHJ

962
Phenoxanol
55066-48-3
DEFHJK

965
Phenyl benzoate
93-99-2
DFHJK

967
Phenyl ethyl benzoate
94-47-3
DHJ

969
Phenylacetaldehyde ethyleneglycol
101-49-5
BCEFGIK


acetal

973
2-(6,6-dimethylbicyclo[3.1.1]hept-2-
30897-75-7
ACFHIJKL


en-2-yl)acetaldehyde

974
Pinocarveol
5947-36-4
BCEFGIJKL

976
Piperonyl acetone
55418-52-5
CEFGJ

978
3a,4,5,6,7,7a-hexahydro-1H-4,7-
68039-44-1
DEFHJK


methanoinden-6-yl pivalate

980
(4aR,8aS)-7-methyloctahydro-1,4-
41724-19-0
CEFGJKL


methanonaphthalen-6(2H)-one

982
p-Menth-3-en-1-ol
586-82-3
BCGIJK

985
(E)-3,3-dimethyl-5-(2,2,3-
107898-54-4
DHJK


trimethylcyclopent-3-en-1-yl)pent-4-


en-2-ol

988
1-methyl-4-(4-methylpent-3-en-1-
52474-60-9
DFHJK


yl)cyclohex-3-ene-1-carbaldehyde

993
Propylene glycol
57-55-6
ACEFGIKL

998
p-Tolyl phenylacetate
101-94-0
DFHJ

1000
Ethyl 2,4,7-decatrienoate
78417-28-4
BDEFHJK

1003
2-benzyl-4,4,6-trimethyl-1,3-dioxane
67633-94-7
DEFHJK

1006
2,4-dimethyl-4-
82461-14-1
BDEFHJK


phenyltetrahydrofuran

1007
(2R,4a′R,8a′R)-3,7′-dimethyl-
41816-03-9
DEFHJK


3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-


spiro[oxirane-2,2′-


[1,4]methanonaphthalene]

1008
(Z)-6-ethylideneoctahydro-2H-5,8-
93939-86-7
BCEFHJKL


methanochromene

1009
2-((S)-1-((S)-3,3-
236391-76-7
DFHJ


dimethylcyclohexyl)ethoxy)-2-


oxoethyl propionate

1010
Methyl 2,2-dimethyl-6-
81752-87-6
ADHIJKL


methylenecyclohexane-1-carboxylate

1012
2-methyl-5-phenylpentan-1-ol
25634-93-9
DEFHJK

1016
4-methyl-2-phenyl-3,6-dihydro-2H-
60335-71-9
BCEFGJK


pyran

1020
Sabinol
471-16-9
BCEFHIJKL

1021
Safrole
94-59-7
BCEFHK

1022
2,2,7,9-tetramethylspiro(5.5)undec-
502847-01-0
DHIJK


8-en-1-one

1023
3-methyl-5-(2,2,3-
65113-99-7
DEFHJK


trimethylcyclopent-3-en-1-yl)pentan-


2-ol

1024
(Z)-2-ethyl-4-(2,2,3-
28219-61-6
DEFHJK


trimethylcyclopent-3-en-1-yl)but-2-


en-1-ol

1025
(E)-2-methyl-4-(2,2,3-
28219-60-5
CHJK


trimethylcyclopent-3-en-1-yl)but-2-


en-1-ol

1026
5-methoxyoctahydro-1H-4,7-
86803-90-9
CHJK


methanoindene-2-carbaldehyde

1027
5-methoxyoctahydro-1H-4,7-
193425-86-4
CHJK


methanoindene-2-carbaldehyde

1028
Sclareol
515-03-7
DEFHJ

1029
Sclareol oxide
5153-92-4
DEFHJK

1031
Selina-3,7(11)-diene
6813-21-4
DEFHJKL

1032
2-(1-(3,3-
477218-42-1
DEFHJ


dimethylcyclohexyl)ethoxy)-2-


methylpropyl


cyclopropanecarboxylate

1033
3-(4-isobutylphenyl)-2-
6658-48-6
DHJK


methylpropanal

1035
Spathulenol
6750-60-3
DEFHJK

1036
Spirambrene
533925-08-5
BCEFHJK

1037
Spirodecane
6413-26-9
BCEFGIJKL

1038
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-
224031-70-3
DGJK


1-one

1042
2-(4-methylthiazol-5-yl)ethan-1-ol
137-00-8
CGIKL

1043
2-(heptan-3-yl)-1,3-dioxolane
4359-47-1
ACEFHIJKL

1045
(Z)-dodec-4-enal
21944-98-9
BDFHJK

1046
tau-Cadinol
5937-11-1
DEFHJK

1047
tau-Muurolol
19912-62-0
DEFHJK

1053
Tetrahydrojasmone
13074-63-0
BDFHIJKL

1057
2,6,10,10-tetramethyl-1-
36431-72-8
BDFHIJKL


oxaspiro[4.5]dec-6-ene

1059
Thiomenthone
38462-22-5
BDEFHIJKL

1060
Thujopsene
470-40-6
BDEFGJKL

1062
Thymol methyl ether
1076-56-8
ADHIJKL

1063
1-(2,2,6-trimethylcyclohexyl)hexan-
70788-30-6
DEFHJK


3-ol

1064
trans, trans-2,4-Nonadienal
5910-87-2
ACHKL

1065
trans, trans-Farnesol
106-28-5
DEFHJK

1066
trans-2, cis-6-Nonadienal
557-48-2
ACHKL

1067
trans-2-Decenal
3913-81-3
ADHKL

1070
trans-2-Nonen-1-al
18829-56-6
ADHKL

1072
trans-3, cis-6-nonadienol
56805-23-3
ACEFHK

1073
trans-4-Decen-1-al
65405-70-1
ADHKL

1075
trans-ambrettolide
51155-12-5
DGJ

1077
trans-beta-ocimene
13877-91-3
ADGIKL

1078
trans-beta-Ocimene
3779-61-1
ADGIKL

1082
trans-Geraniol
106-24-1
BCHIK

1083
trans-Hedione
2570-03-8
DFHJK

1085
7-(1,1-Dimethylethyl)-2H-1,5-
195251-91-3
CEFHJ


benzodioxepin-3(4H)-one

1089
Tricyclone
68433-81-8
DEFHJK

1090
Tridecyl alcohol
112-70-9
DEFGJK

1091
Triethyl citrate
77-93-0
CEFGJ

1093
Methyl 2-((1-hydroxy-3-
144761-91-1
DFHJ


phenylbutyl)amino)benzoate

1095
1-((2E,5Z,9Z)-2,6,10-
28371-99-5
DHJK


trimethylcyclododeca-2,5,9-trien-1-


yl)ethan-1-one

1097
Decahydro-2,6,6,7,8,8-hexamethyl-
338735-71-0
BDEFHJK


2h-indeno(4,5-b)furan

1099
13-methyl oxacyclopentadec-10-en-
365411-50-3
DEFHJK


2-one

1102
Undecanal
112-44-7
BDHJK

1104
(E)-4-methyldec-3-en-5-ol
81782-77-6
BDEFHIJK

1105
Valencene
4630-07-3
BDEFHJK

1107
Valerianol
20489-45-6
DEFHJK

1111
Vanillin isobutyrate
20665-85-4
CHJ

1113
Vaniwhite
5533-03-9
CGIK

1116
(Z)-2-methyl-4-(2,6,6-
68555-62-4
BDFHJK


trimethylcyclohex-2-en-1-yl)but-2-


enal

1117
Methyl 2,4-dihydroxy-3,6-
4707-47-5
CGIJ


dimethylbenzoate

1120
1-methoxy-3a,4,5,6,7,7a-hexahydro-
27135-90-6
ACEFHJKL


1H-4,7-methanoindene

1121
Methyl (Z)-2-((3-(4-(tert-
91-51-0
DFHJ


butyl)phenyl)-2-


methylpropylidene)amino)benzoate

1125
(Z)-hex-3-en-1-yl isobutyrate
41519-23-7
ADEFHJKL

1126
Vertacetal
5182-36-5
BCFHJK

1129
1-((3R,3aR,7R,8aS)-3,6,8,8-
32388-55-9
DHJK


tetramethyl-2,3,4,7,8,8a-hexahydro-


1H-3a,7-methanoazulen-5-yl)ethan-


1-one

1131
Methyl (Z)-2-(((2,4-
68738-99-8
DEFHJ


dimethylcyclohex-3-en-1-


yl)methylene)amino)benzoate

1135
Vetiverol
89-88-3
CEFHIJK

1136
Vetivert Acetate
117-98-6
DEFHJK

1137
Decahydro-3H-spiro[furan-2,5′-
68480-11-5
DEFGJKL


[4,7]methanoindene]

1138
(2Z,6E)-nona-2,6-dienenitrile
67019-89-0
ACEFHKL

1139
(Z)-cyclooct-4-en-1-yl methyl
87731-18-8
BCHJKL


carbonate

1140
(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-
552-02-3
DEFHJK


tetramethyldecahydro-1H-


cyclopropa[e]azulen-4-ol

1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8-
127459-79-4
DHJ


tetrahydronaphthalene-2-carbonitrile

1143
(1S,2S,3S,5R)-2,6,6-
133636-82-5
DEFHJK


trimethylspiro[bicyclo[3.1.1]heptane-


3,1′-cyclohexan]-2′-en-4′-one

1144
1′,1′,5′,5′-tetramethylhexahydro-
154171-76-3
DEFHJK


2′H,5′H-spiro[[1,3]dioxolane-2,8′-


[2,4a]methanonaphthalene]

1145
1′,1′,5′,5′-tetramethylhexahydro-
154171-77-4
DEFHJK


2′H,5′H-spiro[[1,3]dioxolane-2,8′-


[2,4a]methanonaphthalene] K

1146
4-(4-hydroxy-3-
122-48-5
CEFGJ


methoxyphenyl)butan-2-one

1147
(1R,8aR)-4-isopropyl-1,6-dimethyl-
41929-05-9
DEFHJKL


1,2,3,7,8,8a-hexahydronaphthalene




































































































































































































































































































































































































































































































































































































































































































































































































































































































TABLE 2



List of materials with at least one MORV greater than 5 to 10






Number
Material Name
CAS Number
Comment Code








2
2,4-dimethyl-2-(5,5,8,8-tetramethyl-
131812-67-4
DFHJ


5,6,7,8-tetrahydronaphthalen-2-yl)-


1,3-dioxolane

23
3a,5,6,7,8,8b-hexahydro-
823178-41-2
DEFHJK


2,2,6,6,7,8,8-heptamethyl-4H-


indeno(4,5-d)-1,3-dioxole

141
2,4-dimethyl-4,4a,5,9b-
27606-09-3
CEFHJK


tetrahydroindeno[1,2-d][1,3]dioxine

185
(1-methyl-2-((1,2,2-
198404-98-7
DEFHJK


trimethylbicyclo[3.1.0]hexan-3-


yl)methyl)cyclopropyl)methanol

227
Isobornylcyclohexanol
68877-29-2
DEFHJK

230
Isobornyl cyclohexanol
66072-32-0
DEFHJK

246
Indol/Hydroxycitronellal Schiff base
67801-36-9
DEFHJ

248
Hydroxymethyl isolongifolene
59056-64-3
DEFHJK

343
8,8-dimethyl-3a,4,5,6,7,7a-
76842-49-4
DEFHJK


hexahydro-1H-4,7-methanoinden-6-


yl propionate

359
(E)-4-((3aR,4R,7R,7aR)-
501929-47-1
DEFHJK


1,3a,4,6,7,7a-hexahydro-5H-4,7-


methanoinden-5-ylidene)-3-


methylbutan-2-ol

565
Cedryl methyl ether
19870-74-7
BDEFHJK

631
beta-Copaene
18252-44-3
BDEFHJKL

659
2′-isopropyl-1,7,7-
869292-93-3
BDEFHJK


trimethylspiro[bicyclo[2.2.1]heptane-


2,4′-[1,3]dioxane]

674
(4aR,5R,7aS,9R)-2,2,5,8,8,9a-
211299-54-6
DEFHJK


hexamethyloctahydro-4H-4a,9-


methanoazuleno[5,6-d][1,3]dioxole

678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-
57345-19-4
DEFHJ


tetramethyldodecahydro-5H-3,5a-


epoxynaphtho[2,1-c]oxepine

679
2,2,6,6,7,8,8-heptamethyldecahydro-
476332-65-7
DEFHJK


2H-indeno[4,5-b]furan

715
alpha-Cedrene epoxide
13567-39-0
BDEFHJK

758
Acetoxymethyl-isolongifolene
59056-62-1
DEFHJK


(isomers)

1028
Sclareol
515-03-7
DEFHJ

1097
Decahydro-2,6,6,7,8,8-hexamethyl-
338735-71-0
DEFHJK


2h-indeno(4,5-b)furan





































































TABLE 3



List of materials with at least one MORV from 0.5 to less than 1






Number
Material Name
CAS Number
Comment Code








12
1-ethoxy-4-(tert-
181258-89-9
ADEFHJK


pentyl)cyclohexane

19
(3Z)-1-(2-buten-1-yloxy)-3-
888744-18-1
ADEFHJKL


hexene

20
4-(2-methoxypropan-2-yl)-1-
14576-08-0
ADHIJKL


methylcyclohex-1-ene

24
O-Methyl linalool
60763-44-2
ADHIJKL

26
o-Methoxycinnamaldehyde
1504-74-1
ACHK

27
Octanal, 3,7-dimethyl-
25795-46-4
ADGIJKL

53
3,3-Dimethyl-5(2,2,3-
329925-33-9
CEFHJ


Trimethyl-3-Cyclopenten-


1yl)-4-Penten-2-ol

54
n-Hexyl salicylate
6259-76-3
DEFHJ

55
n-Hexyl 2-butenoate
19089-92-0
ADEFHJKL

59
Neryl Formate
2142-94-1
BCEFHJK

72
Methyl-beta-ionone
127-43-5
DHJK

73
Myroxide
28977-57-3
ADGIJKL

81
(E)-3,7-dimethylocta-4,6-
18479-54-4
BCEFGIJK


dien-3-ol

84
(Z)-hex-3-en-1-yl
188570-78-7
BCEFHIKL


cyclopropanecarboxylate

96
Methyl phenyl carbinyl
120-45-6
BCHJK


propionate

97
Methyl phenylacetate
101-41-7
ACEFHIKL

107
2-methyl-6-
91069-37-3
BCEFGIKL


oxaspiro[4.5]decan-7-one

111
Methyl geraniate
2349-14-6
BCHJKL

115
2-ethoxy-4-
5595-79-9
CFGK


(methoxymethyl)phenol

116
Methyl
40203-73-4
ACEFHIKL


cyclopentylideneacetate

125
Methoxymelonal
62439-41-2
ACGIJK

133
((1s,4s)-4-
13828-37-0
BDEFHIJK


isopropylcyclohexyl)methanol

147
Linalyl propionate
144-39-8
BDFHJK

150
Linalyl formate
115-99-1
ACFHJK

151
Linalyl butyrate
78-36-4
BDEFHJK

154
Linalyl acetate
115-95-7
BDHJK

157
Linalool
78-70-6
BCEFGIJK

163
(Z)-hex-3-en-1-yl methyl
67633-96-9
ACEFGKL


carbonate

166
Lepidine
491-35-0
BCEFHIKL

169
L-Carvone
6485-40-1
ACGIJKL

181
Khusinil
75490-39-0
DHJK

191
Isoraldeine
1335-46-2
BDHIJK

194
Isopropylvinylcarbinol
4798-45-2
ACGIKL

198
Isopropyl 2-methylbutyrate
66576-71-4
ACEFGIJKL

201
Isopentyrate
80118-06-5
ADEFGIJKL

204
Isononyl acetate
40379-24-6
BDEFHJKL

205
Isononanol
27458-94-2
BDEFGIKL

213
Isoeugenyl acetate
93-29-8
CFHJK

214
Isoeugenol
97-54-1
CEFHIK

232
Isoborneol
124-76-5
ACEFHIJKL

237
Isoamyl octanoate
2035-99-6
DEFHJK

239
Isoamyl isobutyrate
2050-01-3
ACEFGIJKL

255
Hydrocinnamic acid
501-52-0
CEFHIK

258
Hydratopic alcohol
1123-85-9
BCEFHIK

264
Hexyl propanoate
2445-76-3
ADEFHIKL

270
Hexyl butyrate
2639-63-6
BDEFHJKL

273
Hexyl 2-methylbutanoate
10032-15-2
BDEFHJKL

275
Hexyl 2-furoate
39251-86-0
DEFHJK

282
Heptyl alcohol
111-70-6
ACEFGIKL

283
Heptyl acetate
112-06-1
ADEFHKL

284
Heptaldehyde
111-71-7
ACHIKL

287
Heliotropin
120-57-0
BCGIK

302
Geranyl nitrile
5146-66-7
BCEFHKL

306
Geranyl formate
105-86-2
BCEFHJK

308
Geranyl caprylate
51532-26-4
DEFHJ

310
Geranyl benzoate
94-48-4
DFHJ

312
Geranial
141-27-5
ACHIKL

314
N,2-dimethyl-N-
84434-18-4
BCEFHJK


phenylbutanamide

319
gamma-Terpinene
99-85-4
ADEFGIJKL

346
2-(sec-butyl)cyclohexan-1-
14765-30-1
ADFHIKL


one

354
3-(2-ethylphenyl)-2,2-
67634-14-4
BDHJK


dimethylpropanal

355
2-(tert-butyl)cyclohexyl ethyl
67801-64-3
BDFHJK


carbonate

365
2-(tert-butyl)cyclohexyl ethyl
81925-81-7
ACFHIKL


carbonate

366
Fenchyl alcohol
1632-73-1
ACGIJKL

376
Eucalyptol
470-82-6
ADEFGIJKL

379
Ethyl vanillin acetate
72207-94-4
CHJ

387
Ethyl octanoate
106-32-1
BDEFHJKL

400
Ethyl cinnamate
103-36-6
BCEFHK

412
Ethyl 2-
2511-00-4
BDFHIJKL


(cyclohexyl)propionate

419
d-p-8(9)-Menthen-2-one
5524-05-0
ACGIJKL

420
4-methyl-2-phenyltetrahydro-
94201-73-7
BDEFHJK


2H-pyran

437
Dihydromyrcenol
18479-58-8
ADEFGIJK

438
Dihydrojasmone
1128-08-1
BCFHIJKL

439
Dihydroisophorone
873-94-9
ACEFGIJKL

440
Dihydroeugenol
2785-87-7
CEFHIJK

442
Dihydrocoumarin
119-84-6
BCGIKL

443
Dihydrocarvone
7764-50-3
ACGIJKL

447
Dihydro-alpha-terpinyl
80-25-1
BDEFHIJKL


acetate

448
Dihydro-alpha-ionone
31499-72-6
BDHIJK

454
Dibenzyl ether
103-50-4
DEFHJK

455
Dibutyl o-phthalate
84-74-2
DEFHJ

469
2-pentylcyclopentan-1-one
4819-67-4
BDFHIKL

472
Decyl anthranilate
18189-07-6
DEFHJ

477
Methyl (1s,4s)-1,4-
23059-38-3
ADEFHIJKL


dimethylcyclohexane-1-


carboxylate

481
Cyclohexylethyl acetate
21722-83-8
BDEFHJKL

492
Creosol
93-51-6
BCHIK

495
Cosmene
460-01-5
ADEFGIKL

496
4-cyclohexyl-2-methylbutan-
83926-73-2
BDEFGIJK


2-ol

504
2-benzyl-2-methylbut-3-
97384-48-0
BDHJK


enenitrile

509
Citronellyl nitrile
51566-62-2
BCEFGIKL

510
Citronellyl phenylacetate
139-70-8
DFHJ

512
Citronellyl formate
105-85-1
BCEFGJKL

515
Citronellyl benzoate
10482-77-6
DFHJ

517
Citronellol
106-22-9
BCHIJKL

518
Citronellal
106-23-0
ACHIJKL

522
Citral
5392-40-5
ACHIKL

525
cis-Pinane
6876-13-7
ADEFGIJKL

526
(Z)-3-methyl-2-(pent-2-en-1-
488-10-8
BCHIJKL


yl)cyclopent-2-en-1-one

528
cis-iso-Eugenol
5912-86-7
CEFHIK

535
cis-3-Hexenyl valerate
35852-46-1
BDEFHJKL

536
cis-3-Hexenyl tiglate
67883-79-8
BDEFHJK

538
cis-3-Hexenyl propionate
33467-74-2
ACEFHIKL

540
cis-3-Hexenyl butyrate
16491-36-4
ADEFHJKL

542
cis-3-Hexen-1-ol
928-96-1
ACEFHIKL

547
cis-2-Hexenol
928-94-9
ACEFHIKL

549
Cinnamyl nitrile
4360-47-8
ACEFGIK

554
Cinnamic aldehyde
104-55-2
ACHIK

556
Cinnamyl nitrile
1885-38-7
ACEFGIK

557
Chloroxylenol
88-04-0
BCHIJK

575
Carvacrol
499-75-2
DHIJK

576
Carvone
99-49-0
ACGIJKL

579
Carbitol
111-90-0
BCEFGIK

583
Caproyl alcohol
111-27-3
ACEFGIKL

585
2-(2,2,3-trimethylcyclopent-3-
15373-31-6
ACGIJKL


en-1-yl)acetonitrile

588
Camphor
76-22-2
ACEFGIJKL

602
(E)-2-methyl-4-(2,6,6-
3155-71-3
DHJK


trimethylcyclohex-1-en-1-


yl)but-2-enal

605
Borneol
507-70-0
ACEFHIJKL

617
beta-Pinene epoxide
6931-54-0
ACEFGIJKL

619
beta-Phellandrene
555-10-2
ADEFGIJKL

640
Benzylacetone
2550-26-7
ACEFGIK

641
Benzyl salicylate
118-58-1
DFGJ

645
Benzyl isovalerate
103-38-8
BDEFHJK

647
Benzyl isobutyrate
103-28-6
BCHJK

651
Benzyl butyrate
103-37-7
BCEFHJK

652
Benzyl alcohol
100-51-6
ACEFGIKL

662
1-(3,3-
25225-08-5
ADEFHIJKL


dimethylcyclohexyl)ethyl


formate

664
Anisyl acetate
104-21-2
BCEFGK

665
Anisyl formate
122-91-8
BCEFGK

667
Anethole
104-46-1
ACEFHK

672
Amyl benzoate
2049-96-9
DEFHJK

687
alpha-Terpinyl acetate
80-26-2
BDHJK

699
alpha-methyl-
10528-67-3
BDEFHIK


cyclohexanepropanol

701
alpha-methyl cinnamaldehyde
101-39-3
ACHIK

703
alpha-Isomethylionone
127-51-5
BDHIJK

740
2,5-Dimethyl-4-methoxy-
4077-47-8
ACEFGIJKL


3(2H)-furanone

743
Allyl phenoxyacetate
7493-74-5
BCGK

744
Allyl Phenethyl ether
14289-65-7
ACEFHK

745
Allyl heptanoate
142-19-8
ADEFHJKL

755
N-ethyl-N-(m-
179911-08-1
CEFHJK


tolyl)propionamide

760
3-hydroxybutan-2-one
513-86-0
ACEFGIKL

761
Acetoanisole
100-06-1
BCEFHIK

777
6-Methylquinoline
91-62-3
BCEFHIKL

779
6,8-Diethyl-2-nonanol
70214-77-6
BDEFGIJKL

784
5-Methyl-3-heptanone
541-85-5
ACFGIKL

789
4-Vinylphenol
2628-17-3
BCHIK

796
4-hydroxy-3-methoxy-
458-36-6
CH


cinnamaldehyde

797
4-Ethylguaiacol
2785-89-9
CEFHIK

799
4-Damascol
4927-36-0
BDFHJK

808
3-methyl-4-phenylpyrazole
13788-84-6
CEFHK

810
3-Methyl-1,2-
765-70-8
ACEFGIKL


cyclopentanedione

811
3-Methoxy-5-methylphenol
3209-13-0
BCHIK

812
3-Methoxy-3-Methyl Butanol
56539-66-3
ACGIKL

817
3-Hexenol
544-12-7
ACEFHIKL

819
3,7-dimethyl-2-methylene-6-
22418-66-2
ADFHIJK


octenal

820
3,7-dimethyl-1-octanol
106-21-8
BDEFGIJKL

832
2-Phenylethyl acetate
103-45-7
BCEFHK

835
2-Phenethyl propionate
122-70-3
BCEFHJK

836
2-Pentylcyclopentan-1-ol
84560-00-9
DEFHIKL

838
2-nonanone propylene glycol
165191-91-3
BDEFHJK


acetal

845
2-Methoxy-3-(1-
24168-70-5
BCEFGIK


methylpropyl)pyrazine

846
2-isopropyl-N,2,3-
51115-67-4
ACEFGIJK


trimethylbutyramide

847
2-Isopropyl-5-methyl-2-
35158-25-9
ADFGIJKL


hexenal

848
2-Isopropyl-4-methylthiazole
15679-13-7
ACHIJKL

851
2-Hexen-1-ol
2305-21-7
ACEFHIKL

858
2-Butoxyethanol
111-76-2
ACEFGIKL

875
1,4-Cineole
470-67-7
ADGIJKL

880
1-(2,6,6-Trimethyl-2-
43052-87-5
BDHIJK


cyclohexen-1-yl)-2-buten-1-


one

882
(Z)-3-hepten-1-yl acetate
1576-78-9
ACEFHKL

883
(S)-(1R,5R)-4,6,6-
1196-01-6
ACEFGIJKL


trimethylbicyclo[3.1.1]hept-3-


en-2-one

888
(R)-(−)-Linalool
126-91-0
BCEFGIJK

889
(l)-Citronellal
5949-05-3
ACHIJKL

891
(d)-Citronellal
2385-77-5
ACHIJKL

899
(+)-Citronellol
1117-61-9
BCHIJKL

900
(−)-Citronellol
7540-51-4
BCHIJKL

901
(+)-alpha-Pinene
7785-70-8
ADEFGIJKL

902
(+)-Carvone
2244-16-8
ACGIJKL

903
(−)-alpha-Pinene
7785-26-4
ADEFGIJKL

904
Methyl 2-methylbutyrate
868-57-5
ACEFGIKL

909
Hexyl tiglate
16930-96-4
BDEFHJKL

918
Allyl 2-
68901-15-5
CHJK


(cyclohexyloxy)acetate

921
1,5-
75147-23-8
CFHIJK


dimethylbicyclo[3.2.1]octan-


8-one oxime

931
alpha-acetoxystyrene
2206-94-2
ACEFHIK

940
p-Cymene
99-87-6
ADGIJKL

956
Phenethyl formate
104-62-1
ACEFHK

958
Phenethyl isobutyrate
103-48-0
DHJK

960
Phenethyl tiglate
55719-85-2
DHJK

971
Phenylethyl methacrylate
3683-12-3
DHJK

977
p-
4395-92-0
BDFHK


Isopropylphenylacetaldehyde

981
1,2-dimethyl-3-(prop-1-en-2-
72402-00-7
BCEFGIJKL


yl)cyclopentan-1-ol

983
p-Methoxyphenylacetone
122-84-9
BCEFHK

986
(2Z,5Z)-5,6,7-trimethylocta-
358331-95-0
ADHIJKL


2,5-dien-4-one

987
p-Propyl anisole
104-45-0
ADEFHKL

994
p-t-butyl phenyl acetaldehyde
109347-45-7
BDHJK

995
p-tert-Amyl cyclohexanol
5349-51-9
BDEFHIJK

1001
Racemic alpha-Pinene
80-56-8
ADEFGIJKL

1002
4-(4-hydroxyphenyl)butan-2-
5471-51-2
CEFGIK


one

1004
Rhodinol
141-25-3
BCHIJKL

1005
Ethyl (2,3,6-
93981-50-1
BDEFHJKL


trimethylcyclohexyl)carbonate

1011
1-(3,3-
25225-10-9
ADHIJKL


dimethylcyclohexyl)ethyl


acetate

1017
S)-(+)-Linalool
126-90-9
BCEFGIJK

1018
Sabinene
3387-41-5
ADEFGIJKL

1019
Sabinene hydrate
546-79-2
ADEFGIJKL

1030
Propyl (S)-2-(tert-
319002-92-1
BDEFHJK


pentyloxy)propanoate

1039
Spirolide
699-61-6
BCGIKL

1040
(Z)-5-methylheptan-3-one
22457-23-4
BCEFGIJKL


oxime

1041
1-phenylethyl acetate
93-92-5
ACEFHIK

1051
Tetrahydrogeranial
5988-91-0
ADGIJKL

1052
Tetrahydroionol
4361-23-3
BDEFHIJK

1054
Tetrahydrolinalool
78-69-3
BDEFGIJKL

1055
Tetrahydrolinalyl acetate
20780-48-7
ADEFHJKL

1058
Ethyl (1R,6S)-2,2,6-
22471-55-2
ADEFHIJKL


trimethylcyclohexane-1-


carboxylate

1061
Thymol
89-83-8
BDHIJK

1069
trans-2-Hexenol
928-95-0
ACEFHIKL

1071
trans-2-tert-
5448-22-6
ACGIJKL


Butylcyclohexanol

1074
trans-alpha-Damascone
24720-09-0
BDHIJK

1076
trans-Anethole
4180-23-8
ACEFHK

1079
trans-Cinnamic acid
140-10-3
CEFHK

1081
trans-Dihydrocarvone
5948-04-9
ACGIJKL

1084
trans-Isoeugenol
5932-68-3
CEFHIK

1088
Trichloromethyl phenyl
90-17-5
BDEFGJ


carbinyl acetate

1098
2-mercapto-2-methylpentan-
258823-39-1
ACEFHIJKL


1-ol

1110
Vanillin acetate
881-68-5
CH

1112
Vanitrope
94-86-0
CEFHK

1115
2,2,5-trimethyl-5-
65443-14-3
BDFGIJKL


pentylcyclopentan-1-one

1118
Veratraldehyde
120-14-9
BCGIK

1119
(1R,5R)-4,6,6-
18309-32-5
ACEFGIJKL


trimethylbicyclo[3.1.1]hept-3-


en-2-one

1122
Verdol
13491-79-7
ACGIJKL

1127
4-(tert-butyl)cyclohexyl
10411-92-4
BDEFHJK


acetate

1128
4-(tert-butyl)cyclohexyl
32210-23-4
BDEFHJK


acetate

1133
Vethymine
7193-87-5
CEFGK

1134
4-methyl-4-phenylpentan-2-yl
68083-58-9
BDFHJK


acetate

1141
(Z)-1-((2-
292605-05-1
ADEFHKL


methylallyl)oxy)hex-3-ene









































































































































































































































































































































TABLE 4



List of materials with ALL MORVs from 1 to 5






Num-

CAS
Comment

ber
Material Name
Number
Code








7
3-methoxy-7,7-dimethyl-10-
216970-21-7
BDEFHJK


methylenebicyclo[4.3.1]decane

14
Oxyoctaline formate
65405-72-3
DFHJK

39
2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-
103614-86-4
DEFHIJK


octahydronaphthalen-1-ol

48
Nootkatone
4674-50-4
DHJK

183
Khusimol
16223-63-5
CEFHJK

199
Isopimpinellin
482-27-9
CFGJ

206
Iso3-methylcyclopentadecan-1-one
3100-36-5
DEFGJK

212
Isoeugenyl benzyl ether
120-11-6
DFHJ

215
1-((2S,3S)-2,3,8,8-tetramethyl-
54464-57-2
DHJK


1,2,3,4,5,6,7,8-octahydronaphthalen-


2-yl)ethan-1-one

229
Isobornyl isobutyrate
85586-67-0
BDEFHIJK

260
2,3-dihydro-3,3-dimethyl-1H-indene-
173445-44-8
DHJK


5-propanal

261
3-(3,3-dimethyl-2,3-dihydro-1H-
173445-65-3
DHJK


inden-5-yl)propanal

281
3a,4,5,6,7,7a-hexahydro-1H-4,7-
5413-60-5
CEFGJK


methanoinden-6-yl acetate

329
gamma-Eudesmol
1209-71-8
DFHJK

335
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-
1222-05-5
DEFHJK


hexahydrocyclopenta[g]isochromene

353
(Z)-6-ethylideneoctahydro-2H-5,8-
69486-14-2
CEFGJK


methanochromen-2-one

360
8,8-dimethyl-3a,4,5,6,7,7a-
171102-41-3
DEFHJK


hexahydro-1H-4,7-methanoinden-6-


yl acetate

441
Octahydro-1H-4,7-methanoinden-5-
64001-15-6
DEFHJKL


yl acetate

484
3a,4,5,6,7,7a-hexahydro-1H-4,7-
113889-23-9
DEFHJK


methanoinden-6-yl butyrate

487
3a,4,5,6,7,7a-hexahydro-1H-4,7-
67634-20-2
DEFHJK


methanoinden-5-yl isobutyrate

488
Curzerene
17910-09-7
DHJK

501
(E)-cycloheptadec-9-en-1-one
542-46-1
DEFGJ

566
Cedryl formate
39900-38-4
BDEFHJK

567
Cedryl acetate
77-54-3
DEFHJK

569
Cedrol
77-53-2
DEFHJK

570
5-methyl-1-(2,2,3-
139539-66-5
DEFHJK


trimethylcyclopent-3-en-1-yl)-6-


oxabicyclo[3.2.1]octane

573
Caryophyllene alcohol acetate
32214-91-8
DEFHJK

574
Caryolan-1-ol
472-97-9
DEFHJK

603
Bornyl isobutyrate
24717-86-0
BDEFHIJK

616
beta-Santalol
77-42-9
DEFHJK

621
beta-Patchoulline
514-51-2
BDEFGJKL

624
beta-Himachalene Oxide
57819-73-5
BDFHJK

627
(2,2-dimethoxyethyl)benzene
101-48-4
DHJK

632
beta-Cedrene
546-28-1
BDEFGJKL

663
Anisyl phenylacetate
102-17-0
DFHJ

680
2,2,6,6,7,8,8-heptamethyldecahydro-
647828-16-8
ADEFHJK


2H-indeno[4,5-b]furan

684
alpha-Vetivone
15764-04-2
DHJK

694
alpha-Santalol
115-71-9
DEFHJK

696
alpha-Patchoulene
560-32-7
ADEFHJKL

708
alpha-Gurjunene
489-40-7
BDEFHJKL

712
alpha-Eudesmol
473-16-5
DEFHJK

714
alpha-Cubebene
17699-14-8
ADEFHJKL

726
alpha-Agarofuran
5956-12-7
BDEFHJK

750
Allo-aromadendrene
25246-27-9
BDEFHJKL

764
Acetarolle
744266-61-3
DFHJK

775
7-eip-alpha-Eudesmol
123123-38-6
DEFHJK

776
7-Acetyl-1,1,3,4,4,6-
1506-02-1
DEFHJ


hexamethyltetralin

788
5-Cyclohexadecenone
37609-25-9
DEFGJK

804
3-Thujopsanone
25966-79-4
BDEFHJK

872
10-epi-gamma-Eudesmol
15051-81-7
DFHJK

919
3a,4,5,6,7,7a-hexahydro-1H-4,7-
17511-60-3
CEFHJK


methanoinden-6-yl propionate

927
5-Acetyl-1,1,2,3,3,6-
15323-35-0
DEFHJK


hexamethylindan

933
Patchouli alcohol
5986-55-0
DEFHIJK

978
3a,4,5,6,7,7a-hexahydro-1H-4,7-
68039-44-1
DEFHJK


methanoinden-6-yl pivalate

1007
(2R,4a′R,8a′R)-3,7′-dimethyl-
41816-03-9
DEFHJK


3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-


spiro[oxirane-2,2′-


[1,4]methanonaphthalene]

1022
2,2,7,9-tetramethylspiro(5.5)undec-
502847-01-0
DHIJK


8-en-1-one

1024
(Z)-2-ethyl-4-(2,2,3-
28219-61-6
DEFHJK


trimethylcyclopent-3-en-1-yl)but-2-


en-1-ol

1027
5-methoxyoctahydro-1H-4,7-
193425-86-4
CHJK


methanoindene-2-carbaldehyde

1029
Sclareol oxide
5153-92-4
DEFHJK

1035
Spathulenol
6750-60-3
DEFHJK

1038
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-
224031-70-3
DGJK


1-one

1060
Thujopsene
470-40-6
BDEFGJKL

1089
Tricyclone
68433-81-8
DEFHJK

1107
Valerianol
20489-45-6
DEFHJK

1129
1-((3R,3aR,7R,8aS)-3,6,8,8-
32388-55-9
DHJK


tetramethyl-2,3,4,7,8,8a-hexahydro-


1H-3a,7-methanoazulen-5-yl)ethan-


1-one

1131
Methyl (Z)-2-(((2,4-
68738-99-8
DEFHJ


dimethylcyclohex-3-en-1-


yl)methylene)amino)benzoate

1136
Vetivert Acetate
117-98-6
DEFHJK

1137
Decahydro-3H-spiro[furan-2,5′-
68480-11-5
DEFGJKL


[4,7]methanoindene]

1140
(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-
552-02-3
DEFHJK


tetramethyldecahydro-1H-


cyclopropa[e]azulen-4-ol

1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8-
127459-79-4
DHJ


tetrahydronaphthalene-2-carbonitrile

1143
(1S,2S,3S,5R)-2,6,6-
133636-82-5
DEFHJK


trimethylspiro[bicyclo[3.1.1]heptane-


3,1′-cyclohexan]-2′-en-4′-one

1144
1′,1′,5′,5′-tetramethylhexahydro-
154171-76-3
DEFHJK


2′H,5′H-spiro[[1,3]dioxolane-2,8′-


[2,4a]methanonaphthalene]

1145
1′,1′,5′,5′-tetramethylhexahydro-
154171-77-4
DEFHJK


2′H,5′H-spiro[[1,3]dioxolane-2,8′-


[2,4a]methanonaphthalene] K


















































































































































TABLE 5



List of materials with ALL MORVs greater than 5 to 10






Number
Material Name
CAS Number
Comment Code



248
Hydroxymethyl
59056-64-3
BDEFHJK


isolongifolene



























TABLE 6



List of materials with ALL MORVs from 0.5 to less than 1






Number
Material Name
CAS Number
Comment Code



472
Decyl anthranilate
18189-07-6
DEFHJ

526
(Z)-3-methyl-2-(pent-
488-10-8
BCHIJKL


2-en-1-yl)cyclopent-


2-en-1-one
























Compositions and Methods


A composition comprising a malodor reduction material having an MORV of at least 0.5, from about 0.5 to about 10, from 0.5 to about 10, from about 1 to about 10, or from about 1 to about 5 is disclosed.


In one aspect, said composition comprises a malodor reduction material is selected from the group consisting of Table 1 materials Table 2 materials, Table 3 materials and mixtures thereof; in one aspect said material is selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 33; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 123; 126; 130; 142; 145; 146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 738; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1064; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 302; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 114; 117; 122; 123; 126; 130; 142; 145; 146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 4; 29; 30; 31; 32; 50; 65; 67; 70; 92; 93; 103; 122; 123; 145; 167; 168; 208; 210; 218; 243; 256; 278; 290; 364; 386; 394; 424; 436; 453; 468; 524; 527; 532; 578; 580; 584; 589; 609; 618; 627; 668; 683; 702; 711; 763; 767; 770; 786; 802; 821; 829; 837; 839; 840; 852; 864; 866; 869; 873; 876; 878; 905; 950; 973; 993; 1010; 1037; 1043; 1066; 1070; 1073; 1077; 1078; 1102; 1120; 1125, Table 3 materials 12; 19; 20; 24; 27; 32; 53; 55; 65; 70; 73; 97; 116; 119; 125; 154; 163; 167; 194; 198; 201; 204; 239; 256; 264; 270; 273; 282; 283; 284; 290; 319; 346; 365; 376; 387; 412; 419; 437; 439; 443; 447; 469; 477; 481; 495; 518; 525; 538; 540; 542; 547; 583; 588; 589; 609; 617; 619; 652; 683; 740; 744; 745; 760; 784; 789; 810; 812; 817; 838; 839; 847; 848; 851; 858; 875; 878; 882; 889; 891; 901; 903; 904; 940; 987; 1001; 1010; 1011; 1018; 1041; 1051; 1054; 1055; 1069; 1081; 1098; 1102; 1120; 1127; 1128; 1141.
In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 7; 9; 25; 29; 30; 32; 33; 34; 35; 42; 49; 62; 65; 67; 70; 91; 92; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 126; 130; 142; 145; 159; 167; 168; 178; 186; 189; 190; 192; 193; 208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278; 280; 281; 290; 294; 322; 325; 333; 338; 342; 344; 358; 362; 386; 394; 397; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453; 461; 468; 471; 473; 474; 475; 519; 520; 527; 530; 534; 544; 546; 551; 555; 565; 578; 580; 581; 587; 589; 603; 604; 606; 609; 614; 615; 618; 621; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730; 748; 750; 763; 766; 767; 768; 774; 778; 781; 792; 802; 806; 814; 821; 826; 827; 834; 839; 840; 850; 852; 865; 866; 868; 869; 873; 876; 877; 878; 884; 897; 905; 926; 928; 929; 950; 955; 969; 973; 974; 993; 1006; 1008; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1072; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145 and table 3 materials 9; 12; 19; 21; 25; 32; 34; 53; 55; 59; 65; 70; 81; 84; 97; 98; 108; 110; 114; 116; 119; 126; 133; 142; 147; 150; 157; 159; 163; 166; 167; 178; 189; 192; 198; 201; 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 290; 302; 306; 319; 322; 325; 333; 338; 344; 346; 358; 362; 365; 376; 387; 412; 420; 428; 429; 437; 438; 439; 444; 447; 461; 469; 474; 477; 481; 495; 496; 509; 512; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 579; 583; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 651; 652; 662; 664; 665; 667; 683; 686; 693; 698; 699; 744; 745; 760; 761; 777; 779; 784; 792; 797; 806; 810; 817; 819; 820; 827; 832; 835; 836; 838; 839; 845; 846; 847; 850; 851; 858; 865; 878; 882; 883; 888; 901; 903; 904; 909; 931; 987; 995; 1001; 1008; 1017; 1018; 1019; 1020; 1030; 1031; 1040; 1041; 1053; 1054; 1055; 1057; 1058; 1069; 1076; 1098; 1127; 1128; 1141 and mixtures thereof.
In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147 and mixtures thereof, in one aspect, said composition comprises a material selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147 and mixtures thereof.
In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 4; 13; 16; 17; 18; 21; 32; 33; 34; 35; 37; 42; 49; 57; 76; 126; 145; 156; 167; 168; 174; 190; 199; 206; 208; 210; 242; 247; 249; 259; 277; 281; 286; 289; 318; 353; 370; 371; 372; 373; 378; 407; 417; 424; 425; 429; 449; 457; 468; 474; 479; 480; 482; 485; 501; 524; 527; 529; 537; 562; 578; 580; 587; 589; 592; 595; 612; 615; 618; 621; 632; 638; 639; 649; 683; 702; 711; 733; 735; 736; 741; 748; 767; 771; 786; 788; 824; 834; 839; 866; 868; 877; 905; 924; 955; 969; 974; 976; 980; 982; 993; 1016; 1037; 1038; 1042; 1060; 1075; 1077; 1078; 1090; 1091; 1117; 1137; 1146, Table 3 materials 13; 21; 27; 32; 34; 37; 73; 81; 107; 115; 125; 126; 157; 163; 167; 169; 194; 198; 201; 205; 239; 242; 277; 282; 286; 287; 289; 319; 366; 370; 371; 372; 376; 378; 407; 417; 419; 429; 437; 439; 442; 443; 457; 474; 479; 480; 482; 485; 495; 496; 509; 512; 525; 529; 537; 549; 556; 576; 579; 583; 585; 588; 589; 592; 617; 619; 638; 640; 641; 652; 664; 665; 683; 740; 743; 760; 771; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901; 902; 903; 904; 940; 981; 1001; 1002; 1017; 1018; 1019; 1039; 1040; 1051; 1054; 1071; 1075; 1081; 1088; 1091; 1115; 1118; 1119; 1122; 1133; 114, and mixtures thereof, in one aspect, said composition comprises a material selected from Table 1 materials 4; 21; 32; 33; 34; 35; 42; 49; 145; 167; 168; 190; 208; 210; 259; 281; 424; 429; 449; 468; 474; 524; 527; 578; 580; 587; 589; 612; 615; 618; 621; 632; 639; 649; 683; 702; 711; 748; 767; 786; 834; 839; 866; 868; 877; 905; 955; 969; 974; 982; 993; 1016; 1037; 1060; 1077; 1078; 1137, Table 3 materials 21; 27; 32; 34; 73; 81; 125; 126; 157; 163; 167; 169; 194; 198; 201; 205; 239; 282; 287; 319; 366; 376; 419; 429; 437; 439; 443; 474; 495; 496; 509; 512; 525; 549; 556; 576; 579; 583; 585; 588; 589; 617; 619; 640; 652; 664; 665; 683; 740; 760; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901; 902; 903; 904; 940; 981; 1001; 1017; 1018; 1019; 1039; 1040; 1051; 1054; 1071; 1081; 1115; 1122 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material, in one aspect, comprises a malodor reduction material having a Universal MORV.
Preferably, said composition comprising a malodor reduction material having a Universal MORV comprises a malodor reduction material selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and Table 6 material 627 and mixtures thereof. In one aspect, such materials are selected from Table 4 material 627 and mixtures thereof are disclosed.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV. In one aspect, said composition comprises, a malodor reduction material selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and mixtures thereof are disclosed.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145, Table 5 materials 248, and Table 6 material 472 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 199; 206; 281; 353; 501; 621; 632; 788; 1038; 1060; 1137 and mixtures thereof. In one aspect, such materials are selected from Table 4 281; 621; 632; 1060; 1137 and mixtures thereof.
A composition according to any preceding embodiment wherein said malodor reduction material is not a material selected from the group consisting of 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 and mixtures thereof.
A composition according to any preceding embodiment, said malodor reduction composition being a consumer product, said consumer comprising a total of, based on total consumer product weight, from about 0.0001% to about 100% of one or more of said malodor reduction materials and an adjunct material is disclosed.
In one aspect, said malodor reduction composition that is a consumer product is a laundry detergent that comprises a total of, based on total consumer product weight, from about 0.0001% to about 10%, in one aspect, from about 0.001% to about 5%, in one aspect, from about 0.1% to about 3%, in one aspect, from about 0.3% to about 2% of one or more of said malodor reduction materials and, a material selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, a fabric softener active, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and mixtures thereof, in none aspect, said laundry detergent comprises an adjunct material selected from the group consisting of an organic acid, in one aspect, citric acid and/or lactic acid, hydrogenated castor oil, ethoxylated polyethleneimines, in one aspect, PEI 600 EO 20 and/or PEI 600, an enzyme, in one aspect, a cold water amylase, cold water protease and/or xylogluconase.
In one aspect, said malodor reduction composition that is a consumer product is air care composition that comprises a total of, based on total consumer product weight, from about 0.001% to about 100%, in none apect, from 0.01 to 10%, of one or more of said malodor reduction materials and, optionally, one or more materials selected from the group consisting of surfactants, antimicrobial agents, wetting agents, buffering agents, cyclodextrins, propellants, and solvents.
In one aspect, said malodor reduction composition that is a consumer product is a liquid fabric enhancer that comprises a total of, based on total composition weight, from about 0.05% to about 10% of one or more of said malodor reduction materials and, a fabric softener active selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, in one aspect, said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate, 1,2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride dicanoladimethylammonium methylsulfate, 1-methyl-1-stearoylamidoethyl-2-stearoylimidazolinium methylsulfate, 1-tallowylamidoethyl-2-tallowylimidazoline, Dipalmethyl Hydroxyethylammoinum Methosulfate and mixtures thereof, in one aspect, said fabric softening active has an Iodine Value of between 0-140, in one aspect, 5-100, in one aspect,10-80, in one aspect, 15-70, in one aspect 18-25.
In one aspect, said malodor reduction composition that is a consumer product is a fabric enhancer solid particle or bead composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and at least about 25% PEG 8000.
In one aspect, said malodor reduction composition that is a consumer product is a soluble unit-dose composition contained within a PVA film.
In one aspect, said malodor reduction composition that is a consumer product is a fabric softener dryer added sheet composition, said fabric softener dryer added sheet composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and impregnated onto a non-woven sheet.
In one aspect, said malodor reduction composition that is a consumer product is a spray-dried laundry detergent powder, said composition comprising from about 0.05% to about 20% of one or more of said malodor reduction materials and at least 10% solids chosen from the following list or combinations thereof: sodium carbonate, sodium sulfate, carboxy methyl cellulose powder, a polymer comprising an acrylate monomer.
In one aspect, said malodor reduction composition that is a consumer product is a plastic film said plastic film comprising LLDPE, LDPE, HDPE, and/or compostable film, in one aspect, said plastic film comprises about 0.5 mg to about 100 mg of said malodor reduction composition per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 30 mg per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 15 mg per 20 grams of said plastic film.
In one aspect, said malodor reduction composition that is a consumer product is an absorbent article said absorbent article comprising a total of, based on total consumer product weight, from about 0.1% to about 75%, in one aspect, from about 1% to about 50%, in one aspect, from about 5% to about 40%, in one aspect, from about 12% to about 30% of one or more of said malodor reduction materials and, wherein the article comprises a topsheet, a backsheet, an absorbent core disposed between the topsheet and the backsheet, and an acquisition layer disposed between the topsheet and the absorbent core, wherein the malodor reduction composition is disposed on one of the backsheet, absorbent core, or acquisition layer, in one aspect, said absorbant article comprises a hot melt adhesive and the hot melt adhesive comprises the malodor reduction composition, in one aspect, the hot melt adhesive adheres the backsheet to the topsheet, in one aspect, the backsheet comprises a nonwoven layer and a film layer, and the hot melt adhesive adheres the backsheet nonwoven layer to the backsheet film layer.
In one aspect, said malodor reduction composition that is a consumer product is a personal care deodorant composition, said deodorant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 0.01% to about 75% of an antimicrobial, in one aspect, said antimicrobialsare selected from the group consisting of metals, zeolites, metal zeolites, quaternary ammonium (quat) compounds (e.g., cetyl pyridinium chloride, and benzylalkonium chloride), quat bound clays, metal bound clays, polyaspirin. salicylic acid, polyvinyl amines, coal tar, sulfur, whitfield's ointment, castellani's paint, aluminum chloride, gentian violet, octopirox (piroctone olamine), ciclopirox olamine, undecylenic acid and it's metal salts, potassium permanganate, selenium sulfide, sodium thiosulfate, glycols, diols, oil of bitter orange, urea preparations, griseofulvin, 8-Hydroxyquinoline ciloquinol, thiobendazole, thiocarbamates, haloprogin, polyenes, hydroxypyridone, morpholine, benzylamine, allylamines (such as terbinafine), tea tree oil, clove leaf oil, coriander, palmarosa, berberine, thyme red, cinnamon oil, citronellic acid, hinokitol, ichthyol pale, Sensiva SC-50, Elestab HP-100, azelaic acid, lyticase, iodopropynyl butylcarbamate (IPBC), triclosan, triclocarban, isothiazalinones and azoles, and combinations thereof, more preferably, hexanediol, triclosan, octyl isothiazalinone metals selected from the group consisting of Zn, Cu, Al, Ti, Sn, Bi, and Ag, metal salts selected from the group consisting of zinc carbonate, copper sulfate, and zinc gluconate, metal pyrithione salts selected from the group consisting of ZPT and CuPT, glycols selected from the group consisting of propylene glycol, dipropylene glycol and hexylene glycol and mixtures thereof, in one aspect, said personal care deodorant composition comprises, based on total deodorant weight, from about 10% to about 75% glycol.
In one aspect, said malodor reduction composition that is a consumer product is a personal care body wash/shampoo composition, said body wash/shampoo comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials from about 3% to 30% of a surfactant, and, optionally, a miscellar phase and/or lamellar phase.
In one aspect, said malodor reduction composition that is a consumer product is a personal care antiperspirant composition, said antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.
In one aspect, said malodor reduction composition that is a consumer product is an anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% oof an antiperspirant actives slected from the group consisiting of astringent metallic salts, in one aspect, inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, in one aspect, aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.
In one aspect, said malodor reduction composition that is a consumer product is a dish cleaning composition, said dish cleaning composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials.
In one aspect, a method of controlling malodors comprising: contacting the material comprising a malodor with a composition selected from the group consisting of any of the compositions comprising a malodor reduction material disclosed herein and mixtures thereof, in one aspect, said contacting step comprises contacting said material containing a malodor with about 1 mg to about 50 mg, from about 3 mg to 30 mg, or from about 5 mg to about 20 mg of said composition per 20 grams of said material containing a malodor is disclosed.
In one aspect, a method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV of said material, in one aspect, determining said MORV and/or Universal MORV by the MORV and Universal MORV method provided in Test Method 1, is disclosed.
Process of Making Encapsulates
Methods of making suitable encapsulated malodor reduction compositions, for example condensation processes, as well as suitable shell materials for such encapsulated malodor reduction compositions are described in U.S. Pat. No. 6,869,923 B1 and US Published Patent Applications Nos. 2005/0276831 A1 and 2007/020263 A1. Such shell materials include acrylates, acrylics, aminoplast materials such as melamine formaldehyde material and combinations thereof. Suitable equipment for use in the processes disclosed herein may include continuous stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, ploughshear mixers, ribbon blenders, vertical axis granulators and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. Such equipment can be obtained from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., U.S.A.), Arde Barinco (N.J., U.S.A.).
Adjunct Materials
While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain aspects of the invention, for example to assist or enhance cleaning performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the fabric treatment operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives.
As stated, the adjunct ingredients are not essential to Applicants' compositions. Thus, certain aspects of Applicants' compositions do not contain one or more of the following adjuncts materials: surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems structure elasticizing agents, carriers, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below.
Hueing Dye—The liquid laundry detergent composition may comprise a hueing dye. The hueing dyes employed in the present laundry care compositions may comprise polymeric or non-polymeric dyes, organic or inorganic pigments, or mixtures thereof. In one aspect, the hueing dye comprises a polymeric dye, comprising a chromophore constituent and a polymeric constituent. The chromophore constituent is characterized in that it absorbs light in the wavelength range of blue, red, violet, purple, or combinations thereof upon exposure to light. In one aspect, the chromophore constituent exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers in water and/or methanol, and in another aspect, from about 560 nanometers to about 610 nanometers in water and/or methanol.
Although any suitable chromophore may be used, the dye chromophore is, in one aspect, selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and phthalocyanine dye chromophores. Mono and di-azo dye chromophores are may be preferred.
The hueing dye may comprise a dye polymer comprising a chromophore covalently bound to one or more of at least three consecutive repeat units. It should be understood that the repeat units themselves do not need to comprise a chromophore. The dye polymer may comprise at least 5, or at least 10, or even at least 20 consecutive repeat units.
The repeat unit can be derived from an organic ester such as phenyl dicarboxylate in combination with an oxyalkyleneoxy and a polyoxyalkyleneoxy. Repeat units can be derived from alkenes, epoxides, aziridine, carbohydrate including the units that comprise modified celluloses such as hydroxyalkylcellulose; hydroxypropyl cellulose; hydroxypropyl methylcellulose; hydroxybutyl cellulose; and, hydroxybutyl methylcellulose or mixtures thereof. The repeat units may be derived from alkenes, or epoxides or mixtures thereof. The repeat units may be C 2 -C 4 alkyleneoxy groups, sometimes called alkoxy groups, in one aspect, derived from C 2 -C 4 alkylene oxide. The repeat units may be C 2 -C 4 alkoxy groups, in one aspect, ethoxy groups.
For the purposes of the present invention, the at least three consecutive repeat units form a polymeric constituent. The polymeric constituent may be covalently bound to the chromophore group, directly or indirectly via a linking group. Examples of suitable polymeric constituents include polyoxyalkylene chains having multiple repeating units. In one aspect, the polymeric constituents include polyoxyalkylene chains having from 2 to about 30 repeating units, from 2 to about 20 repeating units, from 2 to about 10 repeating units or even from about 3 or 4 to about 6 repeating units. Non-limiting examples of polyoxyalkylene chains include ethylene oxide, propylene oxide, glycidol oxide, butylene oxide and mixtures thereof.
Surfactants—The compositions according to the present invention may comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof.
The surfactant is typically present at a level of from about 0.1% to about 60%, from about 1% to about 50% or even from about 5% to about 40% by weight of the subject composition.
Chelating Agents—The compositions herein may contain a chelating agent. Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof. When a chelating agent is used, the composition may comprise from about 0.1% to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject composition.
Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
When present in a subject composition, the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.1% to about 3% by weight of the composition.
Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.
Perfumes—The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, α-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
Perfume Delivery Technologies—The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies can also be used to increase the longevity of perfume release from the treated substrate. Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 A1.
In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of: perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:
In one aspect, said perfume delivery technology may comprise microcapsules formed by at least partially surrounding a benefit agent with a wall material. Said benefit agent may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, α-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfume materials can be obtained from Givaudan Corp. of Mount Olive, N.J., USA, International Flavors & Fragrances Corp. of South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsule wall material may comprise: melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. In one aspect, said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. In one aspect, said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. In one aspect, said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. In one aspect, said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. In one aspect, the perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof. In one aspect, the microcapsule may be a perfume microcapsule. In one aspect, one or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.
In one aspect, said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use “reactive” polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery. Nonlimiting examples of polymeric amines include polymers based on polyalkylimines, such as polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric) amines include hydroxyl amines, such as 2-aminoethanol and its alkyl substituted derivatives, and aromatic amines such as anthranilates. The ARPs may be premixed with perfume or added separately in leave-on or rinse-off applications. In another aspect, a material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. In yet another aspect, the aforementioned alternative compounds can be used in combination with amine compounds. In yet another aspect, a single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. No. 6,413,920 B1.
Fabric Softening Actives
The compositions of the present invention may comprise a fabric softening active (“FSA”). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quaternary ammonium compounds (quat), amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty acids, softening oils, polymer latexes and mixtures thereof.
Non-limiting examples of water insoluble fabric care benefit agents include dispersible polyethylene and polymer latexes.
Quat—Suitable quats include but are not limited to, materials selected from the group consisting of ester quats, amide quats, imidazoline quats, alkyl quats, amdioester quats and mixtures thereof. Suitable ester quats include but are not limited to, materials selected from the group consisting of monoester quats, diester quats, triester quats and mixtures thereof. In one aspect, a suitable ester quat is bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.85 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 60 or 15 to 50. In one aspect, the cis-trans-ratio of double bonds of unsaturated fatty acid moieties of the bis (2 hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is from 55:45 to 75:25, respectively. Suitable amide quats include but are not limited to, materials selected from the group consisting of monoamide quats, diamide quats and mixtures thereof. Suitable alkyl quats include but are not limited to, materials selected from the group consisting of mono alkyl quats, dialkyl quats quats, trialkyl quats, tetraalkyl quats and mixtures thereof.
In one embodiment, the fabric softening active is a quaternary ammonium compound suitable for softening fabric in a rinse step. In one embodiment, the fabric softening active is formed from a reaction product of a fatty acid and an aminoalcohol obtaining mixtures of mono-, di-, and, in one embodiment, tri-ester compounds. In another embodiment, the fabric softening active comprises one or more softener quaternary ammonium compounds such, but not limited to, as a monoalkyquaternary ammonium compound, dialkylquaternary ammonium compound, a diamido quaternary compound, a diester quaternary ammonium compound, or a combination thereof.
In one aspect, the fabric softening active comprises a diester quaternary ammonium or protonated diester ammonium (hereinafter “DQA”) compound composition. In certain embodiments of the present invention, the DQA compound compositions also encompass diamido fabric softening actives s and fabric softening actives with mixed amido and ester linkages as well as the aforementioned diester linkages, all herein referred to as DQA.
In one embodiment, the fabric softening agent is chosen from at least one of the following: ditallowoyloxyethyl dimethyl ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, ditallow dimethyl ammonium chloride, dihydrogenatedtallow dimethyl ammonium chloride, ditallowoyloxyethyl methylhydroxyethylammonium methyl sulfate, dihydrogenated-tallowoyloxyethyl methyl hydroxyethylammonium chloride, or combinations thereof.
It will be understood that combinations of softener actives disclosed above are suitable for use in this invention.
Anion A
In the cationic nitrogenous salts herein, the anion A − , which comprises any softener compatible anion, provides electrical neutrality. Most often, the anion used to provide electrical neutrality in these salts is from a strong acid, especially a halide, such as chloride, bromide, or iodide. However, other anions can be used, such as methylsulfate, ethylsulfate, acetate, formate, sulfate, carbonate, fatty acid anions and the like. In one aspect, the anion A may comprise chloride or methylsulfate. The anion, in some aspects, may carry a double charge. In this aspect, A − represents half a group.
Silicone
In one embodiment, the compositions of the present invention may comprise a silicone. Suitable levels of silicone may comprise from about 0.1% to about 70%, alternatively from about 0.3% to about 40%, alternatively from about 0.5% to about 30%, alternatively from about 1% to about 20% by weight of the composition. Useful silicones can be any silicone comprising compound. In one embodiment, the silicone polymer is selected from the group consisting of cyclic silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof. In one embodiment, the silicone is a polydialkylsilicone, alternatively a polydimethyl silicone (polydimethyl siloxane or “PDMS”), or a derivative thereof. In another embodiment, the silicone is chosen from an aminofunctional silicone, amino-polyether silicone, alkyloxylated silicone, cationic silicone, ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylated silicone, quaternary silicone, or combinations thereof.
In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:
[R 1 R 2 R 3 SiO 1/2 ] (j+2) [(R 4 Si(X—Z)O 2/2 ] k [R 4 R 4 SiO 2/2 ] m [R 4 SiO 3/2 ] j

wherein:
j is an integer from 0 to about 98; in one aspect j is an integer from 0 to about 48; in one aspect, j is 0; k is an integer from 0 to about 200, in one aspect k is an integer from 0 to about 50; when k=0, at least one of R 1 , R 2 or R 3 is —X—Z; m is an integer from 4 to about 5,000; in one aspect m is an integer from about 10 to about 4,000; in another aspect m is an integer from about 50 to about 2,000;
R 1 , R 2 and R 3 are each independently selected from the group consisting of H, OH, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, C 1 -C 32 alkoxy, C 1 -C 32 substituted alkoxy and X—Z; each R 4 is independently selected from the group consisting of H, OH, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, C 1 -C 32 alkoxy and C 1 -C 32 substituted alkoxy; each X in said alkyl siloxane polymer comprises a substituted or unsubstituted divalent alkylene radical comprising 2-12 carbon atoms, in one aspect each divalent alkylene radical is independently selected from the group consisting of —(CH 2 ) s — wherein s is an integer from about 2 to about 8, from about 2 to about 4; in one aspect, each X in said alkyl siloxane polymer comprises a substituted divalent alkylene radical selected from the group consisting of: —CH 2 —CH(OH)—CH 2 —; —CH 2 —CH 2 —CH(OH)—; and















each Z is selected independently from the group consisting of















with the proviso that when Z is a quat, Q cannot be an amide, imine, or urea moiety and if Q is an amide, imine, or urea moiety, then any additional Q bonded to the same nitrogen as said amide, imine, or urea moiety must be H or a C 1 -C 6 alkyl, in one aspect, said additional Q is H; for Z A n− is a suitable charge balancing anion. In one aspect A n− is selected from the group consisting of Cl − , Br − , I − , methylsulfate, toluene sulfonate, carboxylate and phosphate; and at least one Q in said organosilicone is independently selected from —CH 2 —CH(OH)—CH 2 —R 5 ;













each additional Q in said organosilicone is independently selected from the group comprising of H, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, —CH 2 —CH(OH)—CH 2 —R 5 ;



















wherein each R 5 is independently selected from the group consisting of H, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, —(CHR 6 —CHR 6 —O—) w -L and a siloxyl residue;
each R 6 is independently selected from H, C 1 -C 18 alkyl
each L is independently selected from —C(O)—R 7 or R 7 ;
w is an integer from 0 to about 500, in one aspect w is an integer from about 1 to about 200; in one aspect w is an integer from about 1 to about 50;
each R 7 is selected independently from the group consisting of H; C 1 -C 32 alkyl; C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl; C 6 -C 32 substituted alkylaryl and a siloxyl residue;
each T is independently selected from H, and















and wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Q in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.
In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:
[R 1 R 2 R 3 SiO 1/2 ] (j+2) [(R 4 Si(X—Z)O 2/2 ] k [R 4 R 4 SiO 2/2 ] m [R 4 SiO 3/2 ] j

wherein
j is an integer from 0 to about 98; in one aspect j is an integer from 0 to about 48; in one aspect, j is 0; k is an integer from 0 to about 200; when k=0, at least one of R 1 , R 2 or R 3 ═—X—Z, in one aspect, k is an integer from 0 to about 50 m is an integer from 4 to about 5,000; in one aspect m is an integer from about 10 to about 4,000; in another aspect m is an integer from about 50 to about 2,000;
R 1 , R 2 and R 3 are each independently selected from the group consisting of H, OH, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, C 1 -C 32 alkoxy, C 1 -C 32 substituted alkoxy and X—Z; each R 4 is independently selected from the group consisting of H, OH, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, C 1 -C 32 alkoxy and C 1 -C 32 substituted alkoxy; each X comprises of a substituted or unsubstituted divalent alkylene radical comprising 2-12 carbon atoms; in one aspect each X is independently selected from the group consisting of —(CH 2 ) s —O—; —CH 2 —CH(OH)—CH 2 —O—;















wherein each s independently is an integer from about 2 to about 8, in one aspect s is an integer from about 2 to about 4;
At least one Z in the said organosiloxane is selected from the group consisting of R 5 ;















provided that when X is









then Z═—OR 5 or













wherein A − is a suitable charge balancing anion. In one aspect A − is selected from the group consisting of Cl − , Br − ,
I − , methylsulfate, toluene sulfonate, carboxylate and phosphate and
each additional Z in said organosilicone is independently selected from the group comprising of H, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, R 5 ,















provided that when X is









then Z═—OR 5 or













each R 5 is independently selected from the group consisting of H; C 1 -C 32 alkyl; C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl or C 6 -C 32 alkylaryl, or C 6 -C 32 substituted alkylaryl,
—(CHR 6 —CHR 6 —O—) w —CHR 6 —CHR 6 -L and siloxyl residue wherein each L is independently selected from —O—C(O)—R 7 or —O—R 7 ;



















w is an integer from 0 to about 500, in one aspect w is an integer from 0 to about 200, one aspect w is an integer from 0 to about 50;
each R 6 is independently selected from H or C 1 -C 18 alkyl;
each R 7 is independently selected from the group consisting of H; C 1 -C 32 alkyl; C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, and C 6 -C 32 substituted aryl, and a siloxyl residue;
each T is independently selected from H;



















wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Z in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.






In one embodiment, the silicone is one comprising a relatively high molecular weight. A suitable way to describe the molecular weight of a silicone includes describing its viscosity. A high molecular weight silicone is one having a viscosity of from about 10 cSt to about 3,000,000 cSt, or from about 100 cSt to about 1,000,000 cSt, or from about 1,000 cSt to about 600,000 cSt, or even from about 6,000 cSt to about 300,000 cSt,
In one embodiment, the silicone comprises a blocky cationic organopolysiloxane having the formula:

M w D x T y Q z wherein: M=[SiR 1 R 2 R 3 O 1/2 ], [SiR 1 R 2 G 1 O 1/2 ], [SiR 1 G 1 G 2 O 1/2 ], [SiG 1 G 2 G 3 O 1/2 ], or combinations thereof; D=[SiR 1 R 2 O 2/2 ], [SiR 1 G 1 O 2/2 ], [SiG 1 G 2 O 2/2 ] or combinations thereof; T=[SiR 1 O 3/2 ], [SiG 1 O 3/2 ] or combinations thereof; Q=[SiO 4/2 ]; w=is an integer from 1 to (2+y+2z); x=is an integer from 5 to 15,000; y=is an integer from 0 to 98; z=is an integer from 0 to 98; R 1 , R 2 and R 3 are each independently selected from the group consisting of H, OH, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, C 6 -C 32 substituted alkylaryl, C 1 -C 32 alkoxy, C 1 -C 32 substituted alkoxy, C 1 -C 32 alkylamino, and C 1 -C 32 substituted alkylamino; at least one of M, D, or T incorporates at least one moiety G 1 , G 2 or G 3; and G 1 , G 2 , and G 3 are each independently selected from the formula:









wherein:
X comprises a divalent radical selected from the group consisting of C 1 -C 32 alkylene, C 1 -C 32 substituted alkylene, C 5 -C 32 or C 6 -C 32 arylene, C 5 -C 32 or C 6 -C 32 substituted arylene, C 6 -C 32 arylalkylene, C 6 -C 32 substituted arylalkylene, C 1 -C 32 alkoxy, C 1 -C 32 substituted alkoxy, C 1 -C 32 alkyleneamino, C 1 -C 32 substituted alkyleneamino, ring-opened epoxide, and ring-opened glycidyl, with the proviso that if X does not comprise a repeating alkylene oxide moiety then X can further comprise a heteroatom selected from the group consisting of P, N and O;
each R 4 comprises identical or different monovalent radicals selected from the group consisting of H, C 1 -C 32 alkyl, C 1 -C 32 substituted alkyl, C 5 -C 32 or C 6 -C 32 aryl, C 5 -C 32 or C 6 -C 32 substituted aryl, C 6 -C 32 alkylaryl, and C 6 -C 32 substituted alkylaryl;
E comprises a divalent radical selected from the group consisting of C 1 -C 32 alkylene, C 1 -C 32 substituted alkylene, C 5 -C 32 or C 6 -C 32 arylene, C 5 -C 32 or C 6 -C 32 substituted arylene, C 6 -C 32 arylalkylene, C 6 -C 32 substituted arylalkylene, C 1 -C 32 alkoxy, C 1 -C 32 substituted alkoxy, C 1 -C 32 alkyleneamino, C 1 -C 32 substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E does not comprise a repeating alkylene oxide moiety then E can further comprise a heteroatom selected from the group consisting of P, N, and O;
E′ comprises a divalent radical selected from the group consisting of C 1 -C 32 alkylene, C 1 -C 32 substituted alkylene, C 5 -C 32 or C 6 -C 32 arylene, C 5 -C 32 or C 6 -C 32 substituted arylene, C 6 -C 32 arylalkylene, C 6 -C 32 substituted arylalkylene, C 1 -C 32 alkoxy, C 1 -C 32 substituted alkoxy, C 1 -C 32 alkyleneamino, C 1 -C 32 substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E′ does not comprise a repeating alkylene oxide moiety then E′ can further comprise a heteroatom selected from the group consisting of P, N, and O;
p is an integer independently selected from 1 to 50;
n is an integer independently selected from 1 or 2;
when at least one of G 1 , G 2 , or G 3 is positively charged, A −t is a suitable charge balancing anion or anions such that the total charge, k, of the charge-balancing anion or anions is equal to and opposite from the net charge on the moiety G 1 , G 2 or G 3; wherein t is an integer independently selected from 1, 2, or 3; and k≦(p*2/t)+1; such that the total number of cationic charges balances the total number of anionic charges in the organopolysiloxane molecule; and wherein at least one E does not comprise an ethylene moiety.


Test Methods


Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and indentified, by analytical methods that include GC-MS and/or NMR.


MORV and Universal MORV Calculation


1.) Search Chemical Abstracts using the name and/or the CAS Registry number for the material of interest and use the structure provided. If there are multiple isomers for a given material, use the structure provided by Chemical Abstracts or use the isomer that is most prevalent in the material. Input structure of material into winMolconn (Hall Associates, version 1.1.2.1).
2.) Input values from 1.) above into the following four equations:


a) MORV=−8.5096+2.8597×( dxp 9)+1.1253×( knotpv )−0.34484×( e 1C2O2)−0.00046231×( idw )+3.3509×( idcbar )+0.11158×( n 2 pag 22)

b) MORV=−5.2917+2.1741×( dxvp 5)−2.6595×( dxvp 8)+0.45297×( e 1C2C2 d )−0.6202×( c 1C2O2)+1.3542×(CdCH2)+0.68105×(C aas C)+1.7129×( idcbar )

c) MORV=−0.0035+0.8028×(SHC satu )+2.1673×( xvp 7)−1.3507×( c 1C1C3 d )+0.61496×( c 1C1O2)+0.00403×( idc )−0.23286×( nd 2).

d) MORV=−0.9926−0.03882×(S d O)+0.1869×(S sp 3OH)+2.1847×( xp 7)+0.34344×( e 1C3O2)−0.45767×( c 1C2C3)+0.7684×(CK etone )
Equation a) is for the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors) Equation b) is for the malodor trimethylamine (amine based malodors) Equation c) is for the malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors) Equation d) is for the malodor skatole (indole based malodors) 3.) For purpose of the present application, a material's MORV is the highest MORV value from equations 2.)a) through 2.)d). 4.) If all MORV values from equations 2.)a) through 2.)d) above are greater than 0.5, the subject material has a Universal MORV.

EXAMPLE 1
Malodor Reduction Composition














MRC A
MRC B
MRC C

Ingredient
CAS #
Percent
Percent
Percent











5-Cyclohexadecen-1-One
37609-25-9
15.0
2.00
2.00

decahydro-2,2,7,7,8,9,9-
476332-65-7
0.005
0.01
0.01

heptamethylindeno(4,3a-b)furan

2,3-Dihydro-5,6-dimethoxy-2-(4-
33704-61-9
0.3
0.5
0.5

piperidinylmethylene)-1H-inden-1-one

Cedryl Methyl Ether
19870-74-7
6.0
10.0
4.0

Trans-4-Decenal
65405-70-1
0.005
0.002
0.002

Decyl Aldehyde
112-31-2
3.74
2.0
2.0

3-methyl cyclopentadecenone
63314-79-4
0.4
1.0
1.0

Diphenyl Oxide
101-84-8
0.5
1.0
1.0

3a,4,5,6,7,7a-hexahydro-4,7-methano-
54830-99-8
5.0
8.0
8.0

1H-indenyl acetate

3a,4,5,6,7,7a-hexahydro-1H-4,7-
68912-13-0
6.0
8.0
8.0

methanoinden-1-yl propanoate

2-(5-methyl-2-propan-2-yl-8-
68901-32-6
10.0
15.0
15.0

bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane

(E)-3,7-dimethyl-2,6-
3681-73-0
10.0
10.0
16.0

octadienylhexadecanoate

Iso Nonyl Acetate
58430-94-7
6.65
8.0
3.0

2,2,7,7-
23787-90-8
10.0
8.0
8.0

tetramethyltricyclo[6.2.1.01,6]undecan-

5-one

(1-Methyl-2-(1,2,2-
198404-98-7
0.1
0.3
0.3

trimethylbicyclo[3.1.0]-hex-3-

ylmethyl)cyclopropyl)methanol

Lauric Aldehyde
112-54-9
0.625
1.0
0.7

Methyl Iso Eugenol
93-16-3
18.000
10.0
13.0

Methyl hexadecanoate
112-39-0
3.000
10.0
12.0

2,3-dihydro-1,1-1H-dimethyl-indene-
300371-33-9
0.400
0.0
0.3

ar-propanal

4-tert-butylcyclohexanol
98-52-2
0.400
0.1
0.1

2-isobutyl-4-hydroxy-4-
63500-71-0
1.600
2.0
2.0

methyltetrahydropyran

Undecyl Aldehyde
112-44-7
1.725
2.888
1.888

Undecylenic Aldehyde
112-45-8
0.550
0.2
1.2

Total

100
100.0
100.0
























































The term “air refresher” or “air freshener”, as used herein, refer to any suitable composition that reduces odors in air, and/or reduces the impression of odors in the air by masking, layering or including malodor counteractant perfume raw materials into the composition.
EXAMPLE 2.1-2.3
Energized Air Refresher
An energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.












Example
Example
Example


2.1
2.2
2.3











Perfume composition
40-60
50-60
30-50

Malodor reducing composition
10-20
15-30
10-25

Functional Perfume Component
30-50
10-30
25-60























Use of Functional Perfume Components at the recited levels may help modulate the evaporation profile of an entire perfume composition to provide perfume character consistency over the intended usage period.
Suitable FPCs may be highly volatile, low boiling, perfume ingredients. Non-limiting, suitable FPCs include iso-nonyl acetate, dihydro myrcenol (3-methylene-7-methyloctan-7-ol), linalool (3-hydroxy-3,7-dimethyl-1,6 octadiene), geraniol (3,7 dimethyl-2,6-octadien-1-ol), d-limonene, 1-methyl-4-isopropenyl-1-cyclohexene, benzyl acetate, isopropyl mystristate, and combinations thereof.

Functional Perfume Component Examples 2.1-2.3













Example A1
Example A2
Example A3











Benzyl alcohol
10-50
0-50
0-20

Iso nonyl acetate
1-20
1-10
1-10

Dipropylene glycol methyl
40-70
5-65
2-50

ether























An energized air freshening device is filled with the composition above. The resulting air freshener is effective at reducing malodor.
EXAMPLES 3.1-3.3
Non-Energized Air Freshener
A non-energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.











Example
Example
Example


3.1
3.2
3.3



Perfume composition
20-30
20-50
10-30

Malodor reducing composition
10-20
10-20
20-50

Functional Perfume components
0-70
40-70
20-70




Example
Example
Example

Functional Perfume components
1
2
3



3a,4,5,6,7,7a-hexahydro-1H-4,7-
15-25
20-25
0-20

methanoinden-1-yl propanoate

Iso nonyl acetate
30-75
15-75
1-10

2-isobutyl-4-hydroxy-4-
20-30
5-65
2-50

methyltetrahydropyran




























A non-energized air freshener is filled with the example composition above. The resulting air freshener is effective at reducing malodor.


EXAMPLES 4.1-4.2
Fabric and Air Refresher Composition
A fabric refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.













Example


Example
Example
4.3

Ingredient
4.1
4.2
(ranges)



Deionized Water
Balance
Balance
Balance

Ethanol
3.0
3.0
1-5.0%

Lupasol HF+
0.0650
0.0650
0-0.1%

Diethylene Glycol
0.175
0.175
0-0.2%

Silwet L-7600
0.1
0.100
0-0.2

Maleic Acid and/or Citric
0.05
0.05
0-0.2

Acid

Koralone B-119
0.015
0.015
0-0.1

Hydroxypropyl β-cyclodextrin
0.630
0.630
0-2.0%

Sodium Hydroxide
0.003
0.003
0.001-0.01

Fragrance
0
0.4%
0-1.0%

Malodor Reduction Composi-
0.03%
0.04%
0-0.1%

tion (MRC A, B, or C)


Total
100.000
100.000
100.000



Lupasol HF Polyethyleneimine (available from BASF)

Silwet L-7600 Organosilicone (available from BASF)

Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical)
































The resulting Fabric fresher composition is effective at reducing or preventing malodor when sprayed on fabrics, such as articles of clothing or upholstery.
EXAMPLE 5.1-5.2
Aerosol Air Freshener Composition
An aerosol air freshener composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.












Ingredient
Example 5.1
Example 5.2












Water Purified USP
Balance
92.370


Ethyl Alcohol
5.000
5.000


Acid Polyacrylic
0.185
—


Sodium Citrate, Dihydrate
—
0.100


Acid Citric Solution 50%
—
0.100


Sodium Dicoctyl
0-0.200
—


Sulfosuccinate


Silwet L-7600
0-0.2
0.200


Hydrogenated Castor Oil
1.400
1.400


PEG 60


Fragrance
0-1.5%
0-1.5%


Malodor Reduction
1.0
0-1.50%


Composition (MRC A, B, or


C)


Hydroxypropyl
0.380
0.380


BetaCyclodextrine


Koralone B-119
0.050
0.050


Sodium Hydroxide 20%
0-0.3
—


Total
100
100





Silwet L-7600 Organosilicone (available from BASF)


Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical)






































A resulting aerosol air freshener is effective at reducing malodor in the air when sprayed. In addition the aerosol can be sprayed on fabrics to reduce or prevent malodor.


EXAMPLES 6.1-6.4
Heavy Duty Liquid Composition


A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.














Example
Example
Example
Example


6.1
6.2
6.3
6.4


WT %
WT %
WT %
WT %

Ingredient
Active
Active
Active
Active











AE 1.8 S
16.3
16.3
12
8

C 11.8 linear alkyl benzene
2.8
2.8
8
—

sulfonic acid

HSAS
13.6
13.6
0
22

C24 alcohol, EO9
2.2
2.2
1
1.8

Citric Acid
0.9
0.9
2
1.7

Lactic Acid
—
5.8
—
—

C 12 -C 18 Fatty Acid
2.3
1.3
0.8
3.0

Protease (55.3 mg/g)
1.7
1.7
1.7
1.7

Amylase (25.4 mg/g)
0.7
0.7
0.7
0.7

Borax
3.6
3.6
3.6
3.6

Calcium Formate
0.2
0.2
0.2
0.2

Polyethyleneimine 600,
1.6
1.6
—
1.6

EO20

Polyethyleneimine 600,
1.6
—
2.0
1.6

EO24, PO16

DTPA
0.3
0.3
0.3
0.3

Tiron ®
0.8
0.8
0.8
0.8

Optical Brightener [7]
0.3
0.3
0.3
0.3

NaOH
4.0
9.3
4.0
9.3

Na Cumene Sulfonate
1.1
1.1
1.1
1.1

Na Formate
0.2
0.2
0.2
0.2

Aesthetics Dye
0.03-1.0
0.03-1.0
0.03-1.0
0.03-1.0

Perfume
0.5-3.0
0.5-3.0
0.5-3.0
0.5-3.0

Malodor Reducing
0.15-1.0
0.15-1.0
0.15-1.0
0.15-1.0

Composition

Water and Solvent
Balance
Balance
Balance
Balance

pH
5.0
8.0
5.0
8.0



HSAS secondary alkyl sulfate, acid form

DTPA diethylene triamine pentaacetic acid (DTPA)

Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate



















































The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.


EXAMPLES 7.1-7.3
Heavy Duty Liquid Composition
Other examples of HDL—Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.











Example
Example
Example


7.1
7.2
7.33


WT %
WT %
WT %

Ingredient
Active
Active
Active



AE 1.8 S
14%
8%
11%

Amine Oxide
2%
—
—

C 11.8 linear alkyl benzene sulfonic
10%
—
—

acid

HSAS
—
20%
15

HF LAS
—
—
—

C24 alcohol, EO9
1%
2%
1.2%

Citric Acid
3%
1.5%
0.9%

C 12 -C 18 Fatty Acid
2%
1%
1.5%

Protease (55.3 mg/g)
0.013
0.8
0.013

Amylase (25.4 mg/g)
0.02
0.7
0.02

Borax
2-8.0
2-8.0
2-8.0

Calcium Formate
0.2
0.2
0.2

Carezyme 5.0L
0.01-0.5
—
0.01-0.5

Polyethyleneimine 600, EO20
0.5-3.0
0.5-3.0
0.5-3.0

Polyethyleneimine 600, EO24,
0.5-3.0
—
0.5-3.0

PO16

DTPA
0.1-1.0
0.1-1.0
0.1-1.0

Tiron ®
0.1-1.5
0.1-1.5
0.1-1.5

Optical Brightener
0.1-1.0
0.1-1.0
0.1-1.0

MEA- Hydrogenated Castor Oil
0.5-3.0
—

NaOH
0.1-1.0
0.1-1.0

Na Cumene Sulfonate
1.1
—

Na Formate
0.2
0.2

Dye
0.1
0.1

Malodor Reducing Composition
0.15-1.0
0.15-1.0
0.15-1.0

Perfume
0.9
0.5-3

Water and Solvent
Balance
Balance
Balance



HSAS secondary alkyl sulfate, acid form

DTPA diethylene triamine pentaacetic acid (DTPA)

Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate















































The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.


EXAMPLES 8.1-8.6
Soluble Uni-Dose Heavy Duty Liquid Composition


An example for a Soluble Uni-dose heavy duty liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.






















3 compartments







pouched product


8.1
8.2
8.3
8.4
8.5
8.6
















Form
liquid
liquid
liquid
liquid
gel
liq
liq
liq

Compartment #
1
1
1
1
1
1
2
3

Dosage (g)
36.0
38.0
32.0
36.0
40.0
34.0
25
35

Alkylbenzene
14.5
13.8
16.0
14.5
13.5
14.5
20.0

sulfonic acid

C 12-14 alkyl
8.5
16.4
10.0
8.5
15.0
8.5

ethoxy 3 sulfate

C 12-13 alkyl 3-



13.0

ethoxylate

C 12-14 alkyl 7-
12.5
9.0
14.0

4.0
12.5
17.0

ethoxylate

C12-18 Fatty
14.5
8.5
16.0
15.0
7.2
14.5
13.0

acid

Citric acid



2.0
4.1

Enzymes
0-3
0-3
0-3

0-3
0-3
0-3

PAP granule 1







50.0

Ethoxysulfated

3.0




2.2

Hexamethylene

Diamine

Dimethyl Quat

Ethoxylated
4.0
1.0

4.0
3.0
2.0

Polyethylenimine

Hydroxyethane
1.0
1.0


1.6
0.6
0.6

diphosphonic

acid

Ethylene



1.0

diamine

tetra(methylene

phosphonic)

acid

Brightener
0.2
0.2
0.3
0.3
0.2
0.2
0.2

Polydimethyl


3.0

Siloxane

Hueing dye 2






0.05

Perfume
1.5-2.0
1.5-2.0
1.5-2.0
1.5-2.0
1.5-2.0
1.5-2.0

Malodor
0.3-0.7
0.3-0.7
0.3-0.7
0.3-0.7
0.3-0.7
0.3-0.7

reducing

composition




Water and
To 100%

minors

Buffers (sodium
To pH 8.0

carbonate,

monoethanolamine)

Solvents (1,2
To 100%

propanediol,

ethanol), Sulfate



1 PAP granule

2 Hueing dye






































































The resulting Unidose pouch product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.


EXAMPLES 9.1-9.5
Fabric Enhancer Solid Particle or Bead Composition


An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example 1.















Example
Example
Example
Example
Example


9.1
9.2
9.3
9.4
9.5


Active
Active
Active
Active
Active

Ingredients
Wt %
Wt %
Wt %
Wt %
Wt %












PEG 8000
86.21
83.255
83.255
86.21
82.49

Free (Neat)
4.41
5.88
4.41
4.25
5.88

Perfume

Malodor
0.75-1.5
0.75-1.5
0.75-1.5
0.75-1.5
0.75-1.5

reducing

composition

Perfume
5.88
8.22
8.88
5.88
8.70

Micro Cap-

sule (PMC)

Encapsulated
1.88
1.88
1.88
1.88
1.88

Perfume

Malodor
1.47
—
1.47
1.63
—

Reducing

Composition

Encapsulated
—
0.75
0.75
—
0.9

Malodor

Reducing

Composition

Aesthetics
0.015
0.015
0.015
0.015
0.015

Dye



1. PMC is a friable PMC with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.

2. Encapsulated perfume (within PMC) assumes about 32% active










































The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.


EXAMPLES 10.1-10.4
Dryer Added Fabric Softener Sheet Composition


An example of a dryer added fabric softener sheet composition prepared with malodor reduction composition, according to the compositions shown in Example 1.














Example
Example
Example
Example


10.1
10.2
10.3
10.4


Wt %
Wt %
Wt %
Wt %

Ingredient
Active
Active
Active
Active











DEQA 1
—
50
—
—

DEQA 2
30
—
—
30

DTDMAMS 3
—
—
50
—

7018FA 4
—
—
50
—

TS-20 5
15
—
—
15

SMS 6
15
—
—
15

SDASA 7
19
25
—
19

TPED 8
—
3
—
—

Complex 9
16.5
16.5
—
8.0

Clay 10
3
4
—
3

Free (Neat) Perfume
1.5
1.5
—
1.5

Free (Neat) malodor
0.5
0.5
0.5
—

reducing compostion

Encapsulated Perfume/
—
—
—
1.56

malodor reducing

composition 11

Encapsulated Perfume 12
—
0.4
—
—

Encap malodor reducing
—
—
—
0.5

composition

Active Weight (g/sheet)
2.4
2.4
1.9
2.4



1 DEQA 1 : Di(soft tallowoyloxyethyl)dimethylammonium methyl sulfate with 25%> 7018 FA, as described below, as solvent

2 DEQA 2 : Di(soft tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with 18% partially hydrogenated tallow fatty acid solvent

3 DTDMAMS: Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate

4 7018FA: 70:30 Stearic Acid:Palmitic Acid (IV = 0) Industrene 7018 sold by Witco

5 TS-20: Polyoxyethylene-20 Sorbitan Tristearate (Glycosperse TS-20, sold by Lonza

6 SMS: Sorbitan Mono Stearate

7 SDASA: 1:2 ratio of stearyl dimethyl amine:triple pressed stearic acid

8 TPED: N,N,N′,N′-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold by BASF)

9 Complex: Beta-Cyclodextrin/Perfume Complex

10 Clay: Calcium Bentonite Clay (Bentonite L sold by Southern Clay Products Free (Neat) Perfume

11 PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/or blocker) is assumed.

12 Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active




















































The compositions of Example 10 are mixed homogeneously and impregnated onto a non-woven polyester sheet having dimensions of about 6% in×12″ (about 17.1 cm×30.5 cm) and weighing about 1 gram.
The resulting dryer added fabric softener sheet product when added to an automatic dryer is effective at reducing malodor on the clothing.


EXAMPLES 11.1-11.4
Liquid Fabric Enhancer Composition


An example of a Liquid Fabric Enhancer composition prepared with malodor reduction composition, according to the compositions shown in Example 1.














Example
Example
Example
Example


11.1
11.2
11.3
11.4


Wt %
Wt %
Wt %
Wt %

Ingredient
Active
Active
Active
Active











FSA 1
12
21
18
14

Low MW alcohol
1.95
3.0
3.0
2.28

Structurant 2,3
1.25 e
—
0.2 f
—

Free (Neat) Perfume
1.50
1.8
2.0
1.50

Free (Neat) malodor
0.3
0.7
—
—

reducing composition

Encapsulated Perfume 4
—
0.6
—
0.6

Encap malodor reducing
—
—
0.6
0.6

composition 4

Perfume/malodor
—
1.85
1.85
3.7

reducing composition

encapsulated 5

Calcium Chloride
0.10
0.12
0.1
0.45

DTPA 6
0.005
0.005
0.005
0.005

Preservative (ppm) 7
5
5
5
5

Antifoam 8
0.015
0.15
0.11
0.011

Polyethylene imines 9
0.15
0.05
—
0.1

Delivery enhancing
0.1
0.1
0.2
0.05

PDMS emulsion 10
—
0.5
1
2.0

Dispersant 11
—
—
0.5
0.2

Organosiloxane
5
—
—
—

Front-end Stability
0.06 11
0.63 12
0.36 11
0.14 12

Aid 12,13

Dye (parts per million
40
11
30
40

ppm)

Ammonium Chloride



0.10

Hydrochloric Acid
0.010
0.01
0.10
0.010

Deionized Water
Balance
Balance
Balance
Balance



1 N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.

2 Cationic high amylose maize starch-available from National Starch under the trade name HYLON VII ®.

3 Cationic polymer available from BASF ® under the name Rheovis ® CDE.

4 Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active

5 PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/or malodor reducing composition) is assumed.

6 Diethylene triamine pentaacetic acid

7 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water available from Dow Chemical under the trade name Koralone B-119

8 Silicone antifoam agent available from Dow Corning ® under the trade name DC2310.

9 Polyethylene imines available from BASF under the trade name Lupasol ®.

10 Polydimethylsiloxane emulsion from Dow Corning ® under the trade name DC346.

11 Non-ionic such as TWEEN 20 ™ or cationic surfactant as Berol 648 and Ethoquad ® C 25 from Akzo Nobel.

12 Organosiloxane polymer condensate made by reacting hexamethylenediisocyanate (HDI), and a, w silicone diol and 1,3-propanediamine, N′-(3-(dimethylamino)propyl)-N,N-dimethyl- Jeffcat Z130) or N-(3-dimethylaminopropyl)-N,Ndiisopropanolamine (Jeffcat

ZR50) commercially available from Wacker Silicones, Munich, Germany.

13 Fineoxocol ® 180 from Nissan Chemical Co.

14 Isofol ® 16 from Sasol.

**For example PGE
































































Examples 11.1 to 11.4 are made by combining the molten fabric softener active with the front-end stability agent to form a first mixture. This first mixture is combined with water and hydrochloric acid using a high shear mixing device to form a second mixture. The adjunct ingredients are combined with the second mixture using low shear mixing to form the fabric enhancing formula.
Examples 11.1 through 11.4 are used by dosing 10 to 60 g of the formula into the rinse liquor for example via dispensing into a clothes washing machine. Clothes are dried on a line or in an automated clothes dryer. The fabrics treated with these formulas have improved feel and scent and are effective at reducing malodor on the clothing.
EXAMPLE 12.1-12.2
Spray-Dried Laundry Detergent Powder Composition and Process of Making It


An example of a Spray-Dried Laundry Detergent Powder composition prepared with malodor reduction composition, according to the compositions shown in Example 1.















Dried

Dried


Slurry
Powder
Slurry
Powder


12.1
12.1
12.2
12.2

Compositions
w/w %
w/w %
w/w %
w/w %











Linear alkyl benzene sulfonate
10.6
15.8
21.3
35.7

Acrylate/maleate copolymer
4.6
6.8
9.4
14.2

Ethylenediame disuccinic acid
1.4
2.1
1.7
2.9

and/or Hydroxyethane dimethylene

phosphonic acid

Sodium carbonate
19.4
26.5
18.8
29.9

Sodium sulfate
28.6
42.4
—
—

Carboxy methyl cellulose polymer
—
—
4.3
7.1

Miscellaneous, such as magnesium
1.4
2.2
2.5
4.2

sulfate, brightener and one or more

stabilizers

Free (Neat) Perfume (spray-on)
—
1.7
—
2.4

Free (Neat) malodor reduction
—
0.5
—
0.6

composition (spray-on)

Water
34.0
2.0
42.0
3.0





































Preparation of Spray-Dried Laundry Detergent Powders.


Aqueous slurry 12.1 having the composition as described above is prepared having a moisture content of 34.0%. Any ingredient added above in liquid form is heated to 70° C., such that the aqueous slurry is never at a temperature below 70° C. At the end of preparation, the aqueous slurry is heated to 80° C. and pumped under pressure (5×10 6 Nm −2 ), into a counter current spray-drying tower with an air inlet temperature of from 290° C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder, which is free-flowing. Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder 12.1 has a moisture content of 2.0 wt %, a bulk density of 310 g/l and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder 12.1 is listed in the table above. Perfume and malodor reduction composition are sprayed onto the composition following the spray dry procedure.
Aqueous slurry 12.2 having the composition as described above is prepared having a moisture content of 42.0%. Any ingredient added above in liquid form is heated to 70° C., such that the aqueous slurry is never at a temperature below 70° C. At the end of preparation, the aqueous slurry is heated to 85° C. and pumped under pressure (from 6.5×10 6 Nm −2 ), into a counter current spray-drying tower with an air inlet temperature of from 275° C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder 12.2, which is free-flowing. Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder has a moisture content of 3.0 wt %, a bulk density of 250 g/l and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder is given in the table above. Perfume and malodor reduction composition are sprayed onto the composition after the spray dry process.


EXAMPLE 13
Plastic Film Example with Malodor Reducing Composition


A plastic film is treated with an Malodor Reduction Composition disclosed in the present specification. Said treatment is accomplished by spraying said Malodor Reduction Composition on the film. Said Malodor Reduction Composition is applied to at a level of 0.1% to 5% based on weight of the film. The Malodor Reduction Composition is found on the surface and may also be absorbed into the plastic film.


EXAMPLE 14
Diaper Example with Malodor Reducing Composition


A diaper article, is treated with a Malodor Reduction Composition disclosed in the present specification. The Malodor Reduction Composition is disposed on one or more areas such as:
the garment-facing side; the body-facing side of the topsheet; the absorbent core; the body-facing side of the backsheet.

The Malodor Reduction Composition may also be disposed on the garment-facing side of the absorbent core and/or on other components such as the garment facing side of a nonwoven dusting layer or body-facing side of a secondary topsheet or acquisition layer. In some embodiments, a topsheet or an acquisition layer may comprise a tissue layer and/or a nonwoven layer, and the malodor reduction composition may be disposed on either the tissue layer or the nonwoven layer. As discussed below, the Malodor Reduction Composition may be in the absorbent article via incorporation into an adhesive. In some embodiments, the Malodor Reduction Composition may be incorporated into the absorbent article via a lotion that is applied to a substrate component of the article. In some embodiments, the malodor reduction composition may be incorporated into the absorbent article via an elastomeric film. In some embodiments, the malodor reduction composition may be in an article by having been incorporated into the making of an article component, including, but not limited to, a film, a nonwoven, AGM, elastics, and/or ink.


EXAMPLE 16.1-16.5
Deodorant Example with Malodor Reducing Composition


An example of Deodorant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.














Ingredient
16.1
16.2
16.3
16.4
16.5



Product Form
Solid
Solid
Solid
Solid
Aerosol


Deodor-
Deodor-
Deodor-
Deodor-
Deodor-


ant
ant
ant
ant
ant or


Control



Body






Spray

dipropylene glycol
48
48
20
30
20

propylene glycol
19.3
19.3
22
—
—

tripopylene glycol
—
—
25
—
—

Glycerine
—
—
—
10
—

PEG -8
—
—
—
20
—

Propylene Glycol 3
1.4
1.4
—
—
—

Myristyl Ether

ethanol
—
—
—
—
QS

Water
QS
QS
QS
QS
—

sodium stearate
5.4
5.4
5.5
5.5
—

tetra sodium EDTA
0.5
0.5
0.05
0.05
—

sodium hydroxide
—
—
0.04
0.04
—

triclosan
—
—
0.3
0.3
—

Neat Perfume
2.8
2.8
2
1.5
1.5

Malodor reducing
—
0.7
1.0
0.5
0.35

composition

Blue 1
0.0009
0.0009
—
—
—

Propellant (1,1
—
—
—
—
40

difluoroethane)



QS - Indicates that this material is used to bring the total to 100%.






































EXAMPLES 17.1-17.3
Body Wash with Malodor Reducing Composition


An example of Body Wash compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.














17.1 Body
17.2Body
17.3Body


Wash
Wash
Wash











Sodium Laureth-3 Sulfate (as 28%
27.85%
27.85%
27.85%

active)

Water
Q.S.
Q.S.
Q.S.

Sodium Lauryl Sulfate (as 29%
10.34
10.34
10.34

active)

Cocamidopropyl Betaine B (30%
4.01
4.01
4.01

active)

Citric Acid
0.18
0.18
0.18

Sodium Benzoate
0.3
0.3
0.3

Disodium EDTA
0.12
0.12
0.12

Methylchloroisothiazolinone/
0.04
0.04
0.04

Methylisothiazolinone

Sodium Chloride
2.35
1.7
1.6

Neat Perfume
1.25
1
2

Malodor reducing composition
0.25
0.175
0.25



QS - indicates that this material is used to bring the total to 100%.


































EXAMPLES 18.1-18.6
Antiperspirant Examples with Malodor Reducing Composition


An example of Antiperspirant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.

















18.1
18.2
18.3
18.4
18.5
18.6


Invisible
Invisible
Invisible
Soft
Soft
Soft


Solid
Solid
Solid
Solid
Solid
Solid














Aluminum
24
24
24
26.5
26.5
26.5

Zirconium

Trichlorohydrex

Glycine Powder

Cyclopentasiloxane
Q.S
Q.S.
Q.S.
Q.S.
Q.S.
Q.S.

Dimethicone
—
—
—
5
5
5

CO-1897 Stearyl
14
14
14
—
—
—

Alcohol NF

Hydrogenated
3.85
3.85
3.85
—
—
—

Castor Oil MP80

Deodorized

Behenyl Alcohol
0.2
0.2
0.2
—
—
—

Tribehenin
—
—
—
4.5
4.5
4.5

C 18-36 acid
—
—
—
1.125
1.125
1.125

triglyceride

C12-15 Alkyl
9.5
9.5
5
—
—
—

Benzoate

PPG-14 Butyl
6.5
6.5
—
0.5
0.5
0.5

Ether

Phenyl
3
—
3
—
—
—

Trimethicone

White Petrolatum
3
—
—
3
3
3

Mineral Oil
1.0
1.0
1.0
—
—
—

Free (Neat)
1.0
0.75
2.0
0.75
1.0
1.25

Perfume

Malodor reducing
0.25
—
0.35
0.175
0.25
0.1

composition

Beta-Cyclodextrin
—
3.0
—
—
—
3.0

complexed with

Malodor reducing

composition

Talc Imperial 250
3.0
3.0
3.0
—
—
—

USP

Polyacrylate
—
—
1.9
—
—
—

Microcapsule

loaded with

Malodor reducing

composition



QS - indicates that this material is used to bring the total to 100%.


























































EXAMPLE 19.1-19.4
Dish Cleansing Composition Examples with Malodor Reducing Composition


An example of Dish cleaning compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.















19.1
19.2
19.3
19.4












Alkyl C 10-14 Ethoxy
26.9
—
—
25.7

Sulphate (AE0.6S)

Alkyl C 10-14 Ethoxy
—
18.7
26.9
—

Sulphate (AE2S)

Sodium alkyl benzene
—
8.0
—
—

sulfonate

C12-14 dimethyl amine
6.1
—
—
4.1

oxide

Cocamido propyl betaine
—
4.5
6.8
3.2

Branched Nonionic:
1.0
0.8
—
—

3-propyl heptanol EO8

PEI600-EO10-PO7
—
—
0.8
—

block polymer

Perfume
0.15-0.3
0.15-0.3
0.15-0.3
0.15-0.3

Malodor Reducing
0.06-0.15
0.06-0.15
0.06-0.15
0.06-0.15

Composition

Ethanol
4.0
5.0
3.0
3.0

Polypropylene glycol
1.1
0.8
1.1
1.1

MW2000

Sodium Chloride
1.3
0.8
1.3
0.5




Minors* and water
to balance up to 100%











































EXAMPLES 20.1-20.4
Heavy Duty Liquid Composition


A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.














Example
Example
Example
Example


20.1
20.2
20.3
20.4


WT %
WT %
WT %
WT %

Ingredient
Active
Active
Active
Active











AE 1.8 S
16
16
12
8

C 11.8 linear alkyl benzene
3
3
8
—

sulfonic acid

HSAS 1
14
14
0
22

C24 alcohol, EO9
2
2
1
2

Citric Acid
1
1
2
2

Lactic Acid
—
6
—
—

C 12 -C 18 Fatty Acid
2
1
1
3

Protease (55.3 mg/g)
2
2
2
2

Amylase (25.4 mg/g)
0.7
0.7
0.7
0.7

Borax
3.6
3.6
3.6
3.6

Calcium Formate
0.2
0.2
0.2
0.2

Polyethyleneimine 600,
1.6
1.6
—
1.6

EO20

Polyethyleneimine 600,
1.6
—
2.0
1.6

EO24, PO16

DTPA 2
0.3
0.3
0.3
0.3

Tiron ® 3
0.8
0.8
0.8
0.8

Optical Brightener
0.3
0.3
0.3
0.3

NaOH
4
9
4
9

Na Cumene Sulfonate
1
1
1
1

Na Formate
0.2
0.2
0.2
0.2

Aesthetics Dye
0.03-1
0.03-1
0.03-1
0.03-1

Perfume
0.5-3
0.5-3
0.5-3
0.5-3

Malodor Reducing
0.1-1
0.1-1
0.1-1
0.1-1

Composition

Water and Solvent
Balance
Balance
Balance
Balance

pH
5
8
5
8


















































The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.


EXAMPLES 21.1-21.3
Heavy Duty Liquid Composition
Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.











Example
Example
Example


21.1
21.2
21.3


WT %
WT %
WT %

Ingredient
Active
Active
Active



AE 1.8 S
14
8
11

Amine Oxide
2
—
—

C 11.8 linear alkyl benzene sulfonic
10%
—
—

acid

HSAS 1
—
20
15

C24 alcohol, EO9
1-2
1-2
1-2

Citric Acid
0.5-3
0.5-3
0.5-3

C 12 -C 18 Fatty Acid
1-2
1-2
1-2

Protease (55.3 mg/g)
0.013-0.8
0.013-0.8
0.013-0.8

Amylase (25.4 mg/g)
0.02-0.7
0.02-0.7
0.02-0.7

Borax
2-8
2-8
2-8

Calcium Formate
0.2
0.2
0.2

Carezyme 5.0L
0.01-0.5
—
0.01-0.5

Polyethyleneimine 600, EO20
0.5-3
0.5-3
0.5-3

Polyethyleneimine 600, EO24,
0.5-3
—
0.5-3

PO16

DTPA 2
0.1-1
0.1-1
0.1-1

Tiron ® 3
0.1-2
0.1-2
0.1-2

Optical Brightener
0.1-1
0.1-1
0.1-1

MEA - Hydrogenated Castor Oil

0.5-3
0.5-3

NaOH
0.1-1
0.1-1
0.1-1

Na Cumene Sulfonate
1.1
—
—

Na Formate
0.2
0.2
0.2

Dye
0.1
0.1
0.1

Malodor Reducing Composition
0.15-1.0
—
0.15-1.0

Encapsulated Malodor Reducing 4
—
0.3-3
—

Perfume
0.5-2
0.5-2
—

Encapsulated Perfume 4
—
—
1.5-3

Water and Solvent
Balance
Balance
Balance



1 HSAS is secondary alkyl sulfate, acid form

2 DTPA is diethylene triamine pentaacetic acid (DTPA)

3 Tiron is 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate

4 Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.

















































The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.


EXAMPLES 22.1-22.3
Fabric Enhancer Solid Particle or Bead Composition


An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example 1.













Example
Example
Example


22.1
22.2
22.3


Active
Active
Active

Ingredients
Wt %
Wt %
Wt %



PEG 8000
80-90
80-90
80-90

Free (Neat) Perfume
3.5-6
4-6
3-5

Malodor reducing composition
0.5-2
0.5-2
0.5-2

Encapsulated Perfume 1
0-2
0-2
2-3

Encapsulated Malodor Reducing
—
0.5-2
—

Composition 1

Dipropylene Glycol
0-6
0-5
0-4.5

Aesthetics Dye
0.015
0.015
0.015




























3. Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.


The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.


EXAMPLE: 23.1-23.6
Malodor Reduction Composition


The following malodor reduction malodor reduction compositions are made by combining the listed ingredients. All ingredients are in weight percent of the total malodor reduction composition.
















Ingredient
CAS#
23.1
23.2
23.3
23.4
23.5
23.6














(3aR,5aS,9aS,9bR)-
6790-58-5
0.1
0.5
0
0
0.5
0.2

3a,6,6,9a-tetramethyl-

2,4,5,5a,7,8,9,9b-

octahydro-1H-

benzo[e][1]benzofuran

7-(3-methylbutyl)-1,5-
362467-67-2
1
0.5
0.07
0.6
0.01
0

benzodioxepin-3-one

triethyl 2-
77-93-0
0.05
0.2
1
0.5
0.09
0.03

hydroxypropane-1,2,3-

tricarboxylate

1,1,2,3,3-pentamethyl-
33704-61-9
1
1
0.5
0.5
0.2
0.2

2,5,6,7-tetrahydroinden-4-

one

(3R,3aS,6S,7R,8aS)-
19870-74-7
2
1
0
2
1
3

octahydro-6-methoxy-

3,6,8,8-tetramethyl-1H-

3a,7-methanoazulene

(5E)-3-
63314-79-4
0.3
0.2
0.43
0
0.15
0.17

methylcyclopentadec-5-

en-1-one

4-(octahydro-4,7-
30168-23-1
0.5
1
0.7
1
0.2
0.4

methano-5H-inden-5-

ylidene)butanal

3a,4,5,6,7,7a-hexahydro-
5413-60-5
3
1
0.5
0.5
1
0.8

4,7-methanoinden-6-yl

acetate

3a,4,5,6,7,7a-hexahydro-
68912-13-0
4
0.8
2
2
0.5
1

1H-4,7-methanoinden-1-yl

propanoate

5-(diethoxymethyl)-1,3-
40527-42-2
0.7
0.5
0
0
1
0

benzodioxole

1,3,4,6,7,8-hexahydro-
1222-05-5
5
8
3
8
10
5

4,6,6,7,8,8-

hexamethylcyclopenta(g)-

2-benzopyran

1-(2,3,8,8-tetramethyl-
54464-57-2
18
25
54
28
20
50

1,3,4,5,6,7-

hexahydronaphthalen-2-

yl)ethanone

2,2,7,7-
23787-90-8
0.6
0.5
0.5
3
1
0

tetramethyltricyclo[6.2.1.0

1,6]undecan-5-one

[(1R,2S)-1-methyl-2-
198404-98-7
0.05
0.5
0
0.18
0.05
0.1

[[(1R,3S,5S)-1,2,2-

trimethyl-3-

bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol

2,4-dimethyl-4,4a,5,9b-
27606-09-3
40
38
26
26
20
10

tetrahydroindeno[1,2-

d][1,3]dioxine

methyl 3-oxo-2-
24851-98-7
15
7
5
15
22
22

pentylcyclopentaneacetate

2-[2-(4-methyl-1-
95962-14-4
5
7
5
10
16
5

cyclohex-3-

enyl)propyl]cyclopentan-

1-one

2,2-
101-48-4
0.4
1
0.5
1
1
0

dimethoxyethylbenzene

(E)-3,3-dimethyl-5-(2,2,3-
107898-54-4
0.2
1
0
0.7
0.2
1

trimethyl-3-cyclopenten-

1-yl)-4-penten-2-ol

octahydro-5-methoxy-4,7-
86803-90-9
0.1
0.3
0.3
0.02
0.1
0.1

methano-1H-indene-2-

carboxaldehyde

1-oxacycloheptadecan-2-
109-29-5 &
3
5
0.5
1
5
1

one &
502-72-7

cyclopentadecanone



TOTAL

100
100
100
100
100
100






















































































Each of the malodor reduction compositions of Examples 23.1 through 23.6 is used in a consumer product by combining the malodor reduction composition at a level of about 0.05% to about 0.35%, based on total consumer product weight, with the consumer product. Then the consumer product is applied to a site on the human body that is in need of malodor reduction. In one aspect, the consumer product is selected from a shampoo, body wash, conditioner and an antiperspirant/deodorant.


EXAMPLES 24.1-24.6
Malodor Reduction Composition


The following malodor reduction malodor reduction compositions are made by combining the listed ingredients. All ingredients are in weight percent of the total malodor reduction composition.
















Ingredient
CAS #
24.1
24.2
24.3
24.4
24.5
24.6














(E)-1-(2,6,6-trimethyl-1-
127-42-4
4
8
2
8
3
2

cyclohex-2-enyl)pent-1-

en-3-one

ethyl dodecanoate
106-
0
1
0
3
0
0


33-2

3a,4,5,6,7,7a-hexahydro-
68912-
8
30
1
4
1
3.5

1H-4,7-methanoinden-1-
13-0

yl propanoate

[1R-
1139-
0
0.3
2
.5
0
0.5

(1R*,4R*,6R*,10S*)]-
30-6

4,12,12-trimethyl-9-

methylene-5-

oxatricyclo[8.2.0.04,6]dodecane

(8E)-cyclohexadec-8-en-
3100-
0
5
0
7
0
0

1-one
36-5

3,5,5-trimethylhexyl
58430-
25
15
50
35
60
56

acetate
94-7

ethyl (2,3,6-
93981-
0
1
0
5
0
0

trimethylcyclohexyl)
50-1

carbonate

2,4-dimethyl-4,4a,5,9b-
27606-
25
10
15
15
16
15

tetrahydroindeno[1,2-
09-3

d][1,3]dioxine

2,2,7,7-
23787-
8
9
5
7
5
5

tetramethyltricyclo[6.2.1.01,
90-8

6]undecan-5-one

(3,5-dimethylcyclohex-3-
67634-
0
0.7
0
.5
0
0

en-1-yl)methanol
16-6

3-(7,7-dimethyl-4-
33885-
30
20
25
15
15
18

bicyclo[3.1.1]hept-3-
52-8

enyl)-2,2-

dimethylpropanal



Total

100
100
100
100
100
100




















































Each of the malodor reduction compositions of Examples 24.1 through 24.6 is used as a perfume component in an air care device at a level of form about 5% to about 100% or in other consumer products by combining the malodor reduction composition at a level of about 0.0003% to about 5% based on total consumer product weight, with the consumer product. Then the consumer product is applied to a site on the human body that is in need of malodor reduction, used in an air care device and/or as a treatment composition to treat a fabric and/or hard surface. In one aspect, the consumer product is selected from a shampoo, body wash, conditioner, an antiperspirant/deodorant and/or a fabric or hard surface cleaner or treatment composition such as a detergent or fabric enhancer.


The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.